A. Adhrija Siva Priya , Annamma John , Divya Vijayan , Aswathy A Mohan , Sam Solomon , H. Padma Kumar
{"title":"Eu3+ substituted Y2Mo4O15 nanophosphors for latent fingerprint detection and pc-LED applications","authors":"A. Adhrija Siva Priya , Annamma John , Divya Vijayan , Aswathy A Mohan , Sam Solomon , H. Padma Kumar","doi":"10.1016/j.materresbull.2025.113764","DOIUrl":null,"url":null,"abstract":"<div><div>A series of Eu<sup>3+</sup> substituted <span><math><mrow><msub><mi>Y</mi><mn>2</mn></msub><mi>M</mi><msub><mi>o</mi><mn>4</mn></msub><msub><mi>O</mi><mn>15</mn></msub></mrow></math></span> nanophosphors was successfully synthesized through combustion method. The structural details of the nanophosphors were confirmed through X-ray diffraction and vibrational spectroscopic studies. These studies reveal that the compounds exist in monoclinic structure with space group <span><math><mrow><mi>P</mi><msub><mn>2</mn><mn>1</mn></msub><mo>/</mo><mi>c</mi></mrow></math></span>. The optical properties of the nanophosphors were explored through diffuse reflectance spectroscopy and photoluminescence studies. Under the excitation of near UV light, Eu<sup>3+</sup> substituted <span><math><mrow><msub><mi>Y</mi><mn>2</mn></msub><mi>M</mi><msub><mi>o</mi><mn>4</mn></msub><msub><mi>O</mi><mn>15</mn></msub></mrow></math></span> phosphors showed emission in the red region. The intensity of red emission was tuned by varying the Eu<sup>3+</sup> concentration and the maximum emission intensity was obtained at <span><math><mrow><mi>x</mi><mo>=</mo><mn>0.5</mn></mrow></math></span>. The luminescence lifetime, correlated color temperature, color purity, chromaticity coordinates and quantum yield measurements suggested that the prepared nanophosphors are promising candidates for luminescence applications. Accordingly, the suitability of the optimized nanophosphor for detection of latent fingerprints and phosphor converted light emitting diode applications was investigated.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"194 ","pages":"Article 113764"},"PeriodicalIF":5.7000,"publicationDate":"2025-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Research Bulletin","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0025540825004714","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
A series of Eu3+ substituted nanophosphors was successfully synthesized through combustion method. The structural details of the nanophosphors were confirmed through X-ray diffraction and vibrational spectroscopic studies. These studies reveal that the compounds exist in monoclinic structure with space group . The optical properties of the nanophosphors were explored through diffuse reflectance spectroscopy and photoluminescence studies. Under the excitation of near UV light, Eu3+ substituted phosphors showed emission in the red region. The intensity of red emission was tuned by varying the Eu3+ concentration and the maximum emission intensity was obtained at . The luminescence lifetime, correlated color temperature, color purity, chromaticity coordinates and quantum yield measurements suggested that the prepared nanophosphors are promising candidates for luminescence applications. Accordingly, the suitability of the optimized nanophosphor for detection of latent fingerprints and phosphor converted light emitting diode applications was investigated.
期刊介绍:
Materials Research Bulletin is an international journal reporting high-impact research on processing-structure-property relationships in functional materials and nanomaterials with interesting electronic, magnetic, optical, thermal, mechanical or catalytic properties. Papers purely on thermodynamics or theoretical calculations (e.g., density functional theory) do not fall within the scope of the journal unless they also demonstrate a clear link to physical properties. Topics covered include functional materials (e.g., dielectrics, pyroelectrics, piezoelectrics, ferroelectrics, relaxors, thermoelectrics, etc.); electrochemistry and solid-state ionics (e.g., photovoltaics, batteries, sensors, and fuel cells); nanomaterials, graphene, and nanocomposites; luminescence and photocatalysis; crystal-structure and defect-structure analysis; novel electronics; non-crystalline solids; flexible electronics; protein-material interactions; and polymeric ion-exchange membranes.