Dynamic heat balance modelling of industrial bioleaching plant: Influence of both environment and operating conditions and heat management improvement

IF 3.9 3区 工程技术 Q2 ENGINEERING, CHEMICAL
C. Loubière , E. Olmos , Y. Menard , A.G. Guezennec
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Abstract

A heat balance model was developed for bioleaching processes in stirred tank reactors, based on mechanistic and semi-empirical models to describe the contribution of each heat transfer phenomena. It was validated based on the cooling power required for two industrial case studies at typical bioleaching temperature of 40 °C and sulfide concentrations of 0.80 and 0.52 %. It was then tested on various scenarios. At high sulfide concentration, heat transfer from pulp addition and aeration was more significant than environmental transfers. This was validated using environmental ranges of values (temperature, wind speed, relative humidity, cloud cover) from either subarctic or equatorial climates. In the case of Finland, 12 % more power was predicted in summer than in winter. Regarding the number of primary tanks, one tank may be removed on the KCC-cascade system to save investments, by accepting a 4 % reduction in conversion rate. Finally, heat loss due to environmental conditions increased as the pyrite concentration decreased, passing from only 12 % with a concentration of 80 to 53 % with a concentration of 10 %. Control of the feeding pulp temperature could reduce the use of heat exchangers, and even eliminate them at low sulphide concentrations.
工业生物浸出厂动态热平衡建模:环境和操作条件的影响及热管理改进
基于机械模型和半经验模型,建立了搅拌槽式反应器中生物浸出过程的热平衡模型,以描述每种传热现象的贡献。在典型的生物浸出温度为40°C,硫化物浓度为0.80%和0.52%时,根据两个工业案例所需的冷却功率进行了验证。然后在各种场景下进行测试。在高硫化物浓度下,纸浆添加和曝气传热比环境传热更显著。使用亚北极或赤道气候的环境值范围(温度、风速、相对湿度、云量)验证了这一点。以芬兰为例,预计夏季的发电量比冬季高出12%。关于主罐的数量,可以在kcc -级联系统上移除一个罐,以节省投资,接受转化率降低4%。最后,环境条件造成的热损失随着硫铁矿浓度的降低而增加,从浓度为80时的12%到浓度为10%时的53%。控制进浆温度可以减少换热器的使用,甚至可以在低硫化物浓度下消除换热器。
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来源期刊
Chemical Engineering Research & Design
Chemical Engineering Research & Design 工程技术-工程:化工
CiteScore
6.10
自引率
7.70%
发文量
623
审稿时长
42 days
期刊介绍: ChERD aims to be the principal international journal for publication of high quality, original papers in chemical engineering. Papers showing how research results can be used in chemical engineering design, and accounts of experimental or theoretical research work bringing new perspectives to established principles, highlighting unsolved problems or indicating directions for future research, are particularly welcome. Contributions that deal with new developments in plant or processes and that can be given quantitative expression are encouraged. The journal is especially interested in papers that extend the boundaries of traditional chemical engineering.
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