Encompassing Synthetic Methods to Modification Strategies: Cu-MOF-Derived Electrocatalysts for Enhancing CO2 Reduction

IF 8.8 2区 化学 Q1 Chemistry
Zhi-wei Yu, Ting-ting Huang, Chang-yi Deng, Juan Xiao, Hui Ding, Guan-cheng Xu, Li Zhang
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引用次数: 0

Abstract

To address the global climate challenge, carbon emissions reduction and carbon neutrality have emerged as pivotal goals for the international community. Copper-based metal–organic framework (Cu-MOF) derivatives exhibit unique advantages in electrocatalytic carbon dioxide reduction reaction (CO2RR) applications due to their controllable pore structure, abundant active sites, and efficient charge transport. Nevertheless, the structure–activity correlation mechanisms and performance enhancement methodologies of Cu-MOF derivatives have not yet been comprehensively elucidated in existing literature. This review systematically summarizes the recent advancements in Cu-MOF derivatives for electrocatalytic CO2RR, focusing on preparation technologies such as the pyrolysis method, electrochemical in situ reconstruction method, and other methods. Subsequently, we investigated the enhancement mechanism of the reactivity of electrocatalysts by discussing multidimensional aspects, which include structural design, metal composition adjustment, ligand engineering, and composite structure construction. Finally, the critical challenges and future research directions of Cu-MOF derivatives for electrocatalytic CO2RR are prospectively discussed, which aims to provide theoretical references for the design methods and modification strategies of Cu-MOF derivatives.

Graphical Abstract

This manuscript highlights the application of copper-based metal–organic framework (Cu-MOF) derivatives in electrocatalytic CO2 reduction reaction (CO2RR). We specifically carry out the following three key aspects: synthesis methods of Cu-MOF derivatives, modification strategies, and prospects. It aims to propose rational synthesis methods and modification strategies for the preparation of Cu-MOF-derived electrocatalysts with superior CO2RR performance.

包括合成方法到修饰策略:cu - mof衍生电催化剂增强CO2还原
为应对全球气候挑战,减少碳排放和实现碳中和已成为国际社会的关键目标。铜基金属有机骨架(Cu-MOF)衍生物具有孔隙结构可控、活性位点丰富、电荷传输效率高等特点,在电催化二氧化碳还原反应(CO2RR)中具有独特的应用优势。然而,Cu-MOF衍生物的构效相关机制和性能增强方法在现有文献中尚未得到全面阐述。本文系统总结了电催化CO2RR用Cu-MOF衍生物的最新研究进展,重点介绍了热解法、电化学原位重构法等制备技术。随后,我们从结构设计、金属成分调整、配体工程和复合结构构建等多维方面探讨了电催化剂反应性的增强机理。最后,对电催化CO2RR用Cu-MOF衍生物面临的关键挑战和未来的研究方向进行了展望,旨在为Cu-MOF衍生物的设计方法和修饰策略提供理论参考。摘要本文重点介绍了铜基金属有机骨架(Cu-MOF)衍生物在电催化CO2还原反应(CO2RR)中的应用。本文重点从Cu-MOF衍生物的合成方法、修饰策略和展望三个方面进行了阐述。旨在为制备具有优异CO2RR性能的cu - mof衍生电催化剂提出合理的合成方法和改性策略。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Topics in Current Chemistry
Topics in Current Chemistry 化学-化学综合
CiteScore
11.70
自引率
1.20%
发文量
0
审稿时长
6-12 weeks
期刊介绍: Topics in Current Chemistry provides in-depth analyses and forward-thinking perspectives on the latest advancements in chemical research. This renowned journal encompasses various domains within chemical science and their intersections with biology, medicine, physics, and materials science. Each collection within the journal aims to offer a comprehensive understanding, accessible to both academic and industrial readers, of emerging research in an area that captivates a broader scientific community. In essence, Topics in Current Chemistry illuminates cutting-edge chemical research, fosters interdisciplinary collaboration, and facilitates knowledge-sharing among diverse scientific audiences.
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