Decahedron-derived five-fold twin noble metal nanocrystals: Solution-phase synthesis, growth mechanism, and applications

IF 19.3 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science Pub Date : 2025-08-30 DOI:10.1016/j.cis.2025.103650

Nan Hou , Haihong Wen , Wei Chen , Yun Yang , Bo Jiang , Wei Wang , Shaoming Huang , Shun Wang

{"title":"Decahedron-derived five-fold twin noble metal nanocrystals: Solution-phase synthesis, growth mechanism, and applications","authors":"Nan Hou , Haihong Wen , Wei Chen , Yun Yang , Bo Jiang , Wei Wang , Shaoming Huang , Shun Wang","doi":"10.1016/j.cis.2025.103650","DOIUrl":null,"url":null,"abstract":"<div><div>Five-fold twinned (FFT) noble metal nanocrystals have attracted considerable interest in nanoscience due to their unique structures. This review gives a comprehensive analysis on four common types of FFT noble metal NCs (Au, Ag, Pd, and Pt) synthesized in solution, covering both monometallic structures (e.g., nanodecahedra, nanorods, nanowires, nanobipyramids, and their derivatives) and multimetallic heterostructures, with a brief discussion on FFT Cu nanowires and Rh nanodecahedra. We start with a clear overview of their structural properties, thermodynamic and kinetic stability, and twinning behavior, which is followed by a detailed discussion of key synthetic methods and growth mechanisms driving their development. Next, we provide a summary of their applications. Finally, the review also includes personal insights and identifies future challenges, suggesting potential research directions in this field.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"346 ","pages":"Article 103650"},"PeriodicalIF":19.3000,"publicationDate":"2025-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advances in Colloid and Interface Science","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0001868625002611","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}

引用次数: 0

Abstract

Five-fold twinned (FFT) noble metal nanocrystals have attracted considerable interest in nanoscience due to their unique structures. This review gives a comprehensive analysis on four common types of FFT noble metal NCs (Au, Ag, Pd, and Pt) synthesized in solution, covering both monometallic structures (e.g., nanodecahedra, nanorods, nanowires, nanobipyramids, and their derivatives) and multimetallic heterostructures, with a brief discussion on FFT Cu nanowires and Rh nanodecahedra. We start with a clear overview of their structural properties, thermodynamic and kinetic stability, and twinning behavior, which is followed by a detailed discussion of key synthetic methods and growth mechanisms driving their development. Next, we provide a summary of their applications. Finally, the review also includes personal insights and identifies future challenges, suggesting potential research directions in this field.

Abstract Image

查看原文本刊更多论文

十面体衍生的五重双贵金属纳米晶体：固相合成、生长机制和应用

五重孪晶（FFT）贵金属纳米晶体以其独特的结构引起了纳米科学领域的广泛关注。本文综述了在溶液中合成的四种常见的FFT贵金属NCs (Au、Ag、Pd和Pt)，包括单金属结构（如纳米十面体、纳米棒、纳米线、纳米金字塔及其衍生物）和多金属异质结构，并对FFT Cu纳米线和Rh纳米十面体进行了简要的讨论。我们首先对它们的结构性质、热力学和动力学稳定性以及孪生行为进行了清晰的概述，然后详细讨论了关键的合成方法和驱动它们发展的生长机制。接下来，我们将简要介绍它们的应用。最后，综述还包括个人的见解和未来的挑战，提出了该领域的潜在研究方向。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Advances in Colloid and Interface Science 化学-物理化学

CiteScore

28.50

自引率

2.60%

发文量

175

审稿时长

31 days

期刊介绍： "Advances in Colloid and Interface Science" is an international journal that focuses on experimental and theoretical developments in interfacial and colloidal phenomena. The journal covers a wide range of disciplines including biology, chemistry, physics, and technology. The journal accepts review articles on any topic within the scope of colloid and interface science. These articles should provide an in-depth analysis of the subject matter, offering a critical review of the current state of the field. The author's informed opinion on the topic should also be included. The manuscript should compare and contrast ideas found in the reviewed literature and address the limitations of these ideas. Typically, the articles published in this journal are written by recognized experts in the field.