Emerging processing guidelines for solid electrolytes in the era of oxide-based solid-state batteries†

IF 39 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Moran Balaish, Kun Joong Kim, Hyunwon Chu, Yuntong Zhu, Juan Carlos Gonzalez-Rosillo, Lingping Kong, Haemin Paik, Steffen Weinmann, Zachary D. Hood, Jesse Hinricher, Lincoln J. Miara and Jennifer L. M. Rupp
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Abstract

The current most mature, competitive, and dominant battery technology for electric vehicles (EVs) is the Li-ion battery (LIB). As future EVs will rely on battery technology, further innovation is essential for the success of mobility electrification towards improving the driving range and reducing the charging time and price competitiveness. The commonly cited next generation technologies are hybrid and solid-state batteries (SSBs) enabling high energy densities using lithium. Through a critical approach, we dismantle the oxide-based solid-state battery electrolytes, their chemistries and ceramic manufacture. We evaluate the relevance of solid-state electrolytes and their integration into battery types compared to Li-ion batteries considering a holistic life cycle thinking of sustainable battery production. We evaluate the relevant oxide-based materials and requirements, the material supply chain, and diverse recycling concepts. We raise critical questions about the development of oxide-based SSBs mainly for large-scale production and EV applications, which demand attention to fill current scientific and technological gaps. Next, we critically discuss three major ceramic synthesis routes toward oxide-based solid electrolytes: solid-state processing, wet-chemical solution processing, and vapor deposition. In-depth processing guidelines, hindrances, and opportunities are highlighted. Through a high-level approach, the advantages and disadvantages of each processing method are introduced, while accounting for four major processing metrics applicable for obtaining high Li-ion conducting solid-state Li oxide electrolytes: chemistry of the precursors, dopants and stoichiometry, synthesis temperature, and atmosphere and pressure. We broaden the processing discussion from a single electrolyte component to electrode/electrolyte tandems examining interfaces during cell fabrication, possible cell architectures, design-specific processing methods, challenges, and mitigating solutions for both bulk-type batteries and thin film batteries. Finally, future perspectives and key guidelines for the realization of all SSBs are analyzed and discussed.

Abstract Image

氧化物基固态电池时代固体电解质的新兴加工指南。
目前最成熟、最具竞争力、最具主导地位的电动汽车电池技术是锂离子电池(LIB)。由于未来的电动汽车将依赖于电池技术,进一步的创新对于移动电气化的成功至关重要,以提高行驶里程,减少充电时间和价格竞争力。通常提到的下一代技术是混合电池和固态电池(ssb),它们可以使用锂实现高能量密度。通过一种关键的方法,我们拆除了基于氧化物的固态电池电解质,它们的化学和陶瓷制造。考虑到可持续电池生产的整体生命周期思维,我们评估了固态电解质及其与锂离子电池类型集成的相关性。我们评估相关的氧化物基材料和要求、材料供应链和各种回收概念。我们提出了主要用于大规模生产和电动汽车应用的氧化基固态燃料的关键问题,这些问题需要关注以填补当前的科学和技术空白。接下来,我们批判性地讨论了三种主要的氧化基固体电解质陶瓷合成路线:固态加工、湿化学溶液加工和气相沉积。深入加工的指导方针,障碍和机会突出。通过高层次的方法,介绍了每种加工方法的优缺点,同时考虑了适用于获得高锂离子导电性固态氧化锂电解质的四个主要加工指标:前驱体化学、掺杂剂和化学计量学、合成温度、大气和压力。我们将加工讨论从单一电解质组件扩展到电极/电解质串联,检查电池制造过程中的接口,可能的电池结构,设计特定的加工方法,挑战和减轻解决方案,适用于散装型电池和薄膜电池。最后,分析和讨论了实现所有SSBs的未来前景和关键指导方针。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Chemical Society Reviews
Chemical Society Reviews 化学-化学综合
CiteScore
80.80
自引率
1.10%
发文量
345
审稿时长
6.0 months
期刊介绍: Chemical Society Reviews is published by: Royal Society of Chemistry. Focus: Review articles on topics of current interest in chemistry; Predecessors: Quarterly Reviews, Chemical Society (1947–1971); Current title: Since 1971; Impact factor: 60.615 (2021); Themed issues: Occasional themed issues on new and emerging areas of research in the chemical sciences
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