Electrospinning Polymethyl Methacrylate (PMMA)/UiO-66 for Hydrogen Generation via NaBH4 Hydrolysis

IF 3.7 2区 化学 Q2 CHEMISTRY, APPLIED
Hani Nasser Abdelhamid
{"title":"Electrospinning Polymethyl Methacrylate (PMMA)/UiO-66 for Hydrogen Generation via NaBH4 Hydrolysis","authors":"Hani Nasser Abdelhamid","doi":"10.1002/aoc.70382","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>Metal–organic framework (MOF) using UiO-66 as a model was fabricated into nanofibers via electrospinning with poly(methyl methacrylate) (PMMA), denoted as PUiO-66. The materials, containing different Ui-O66 loadings, were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR), diffuse reflectance spectroscopy (DRS), and Tauc plots. Electrospun PUiO-66 exhibits a nanostructure with nanofiber diameters in the 150–400-nm range. UiO-66-derived polymer nanofibers (PUiO-66) were reported for hydrogen production via the photocatalytic hydrolysis of sodium borohydride (NaBH<sub>4</sub>). UiO-66 was integrated into electrospun PMMA fibers at varying loadings (0.2%, 0.5%, and 1.0%). The shape and homogeneity of the fibers were evaluated via SEM, while their optical properties were studied through DRS and Tauc plots, indicating a decrease in optical bandgap with high UiO-66 loading. The PUiO-66 (1%) demonstrated the maximum catalytic activity, attaining a hydrogen generating rate (HGR) of 500 mL/g<b>·</b>min, about five times higher than that of the PUiO-66 (0.2%). The photocatalytic activity significantly decreased the reaction time, demonstrating the effect of UV absorption of the PUiO-66 fibers on NaBH<sub>4</sub> hydrolysis. The influence of NaBH<sub>4</sub> concentration on hydrogen production was examined, revealing that increased reactant loading markedly enhanced the reaction rate and decreased time for the hydrolysis. The photocatalytic performance of the fibers can be recycled for five successive cycles without a significant drop in the material's performance. Our findings reveals the promising of PUiO-66 nanofibers for effective hydrogen production via photocatalytic hydrolysis of NaBH<sub>4</sub>.</p>\n </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 10","pages":""},"PeriodicalIF":3.7000,"publicationDate":"2025-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Organometallic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/aoc.70382","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0

Abstract

Metal–organic framework (MOF) using UiO-66 as a model was fabricated into nanofibers via electrospinning with poly(methyl methacrylate) (PMMA), denoted as PUiO-66. The materials, containing different Ui-O66 loadings, were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR), diffuse reflectance spectroscopy (DRS), and Tauc plots. Electrospun PUiO-66 exhibits a nanostructure with nanofiber diameters in the 150–400-nm range. UiO-66-derived polymer nanofibers (PUiO-66) were reported for hydrogen production via the photocatalytic hydrolysis of sodium borohydride (NaBH4). UiO-66 was integrated into electrospun PMMA fibers at varying loadings (0.2%, 0.5%, and 1.0%). The shape and homogeneity of the fibers were evaluated via SEM, while their optical properties were studied through DRS and Tauc plots, indicating a decrease in optical bandgap with high UiO-66 loading. The PUiO-66 (1%) demonstrated the maximum catalytic activity, attaining a hydrogen generating rate (HGR) of 500 mL/g·min, about five times higher than that of the PUiO-66 (0.2%). The photocatalytic activity significantly decreased the reaction time, demonstrating the effect of UV absorption of the PUiO-66 fibers on NaBH4 hydrolysis. The influence of NaBH4 concentration on hydrogen production was examined, revealing that increased reactant loading markedly enhanced the reaction rate and decreased time for the hydrolysis. The photocatalytic performance of the fibers can be recycled for five successive cycles without a significant drop in the material's performance. Our findings reveals the promising of PUiO-66 nanofibers for effective hydrogen production via photocatalytic hydrolysis of NaBH4.

电纺丝聚甲基丙烯酸甲酯(PMMA)/UiO-66水解制氢研究
以UiO-66为模型,用聚甲基丙烯酸甲酯(PMMA)静电纺丝制备了金属有机骨架(MOF)纳米纤维,命名为PUiO-66。采用x射线衍射(XRD)、透射电子显微镜(TEM)、扫描电子显微镜(SEM)、傅里叶变换红外(FT-IR)、漫反射光谱(DRS)和tac图对不同负载量的材料进行了表征。静电纺PUiO-66呈现出直径在150 ~ 400 nm范围内的纳米结构。报道了uio -66衍生的聚合物纳米纤维(PUiO-66)通过光催化水解硼氢化钠(NaBH4)制氢。UiO-66以不同的负载(0.2%,0.5%和1.0%)整合到静电纺PMMA纤维中。通过SEM对光纤的形状和均匀性进行了评价,同时通过DRS和Tauc图对光纤的光学特性进行了研究,结果表明高UiO-66负载可以减小光纤的光带隙。PUiO-66(1%)的催化活性最高,产氢率(HGR)为500 mL/g·min,是PUiO-66(0.2%)的5倍左右。光催化活性显著缩短了反应时间,表明PUiO-66纤维的紫外吸收对NaBH4水解有影响。研究了NaBH4浓度对产氢的影响,结果表明,增加反应物负荷显著提高了反应速率,缩短了水解时间。纤维的光催化性能可以连续循环5次而不会显著降低材料的性能。我们的发现揭示了PUiO-66纳米纤维通过光催化水解NaBH4有效制氢的前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Applied Organometallic Chemistry
Applied Organometallic Chemistry 化学-无机化学与核化学
CiteScore
7.80
自引率
10.30%
发文量
408
审稿时长
2.2 months
期刊介绍: All new compounds should be satisfactorily identified and proof of their structure given according to generally accepted standards. Structural reports, such as papers exclusively dealing with synthesis and characterization, analytical techniques, or X-ray diffraction studies of metal-organic or organometallic compounds will not be considered. The editors reserve the right to refuse without peer review any manuscript that does not comply with the aims and scope of the journal. Applied Organometallic Chemistry publishes Full Papers, Reviews, Mini Reviews and Communications of scientific research in all areas of organometallic and metal-organic chemistry involving main group metals, transition metals, lanthanides and actinides. All contributions should contain an explicit application of novel compounds, for instance in materials science, nano science, catalysis, chemical vapour deposition, metal-mediated organic synthesis, polymers, bio-organometallics, metallo-therapy, metallo-diagnostics and medicine. Reviews of books covering aspects of the fields of focus are also published.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信