Characterization and crystallization mechanism of SiO₂-Al₂O₃-Li₂O glass–ceramic using non-isothermal models

IF 2.1 4区 材料科学 Q2 MATERIALS SCIENCE, CERAMICS
Abdelheq Layachi, Soufyane Satha, Maurice François Gonon, Hamid Satha
{"title":"Characterization and crystallization mechanism of SiO₂-Al₂O₃-Li₂O glass–ceramic using non-isothermal models","authors":"Abdelheq Layachi,&nbsp;Soufyane Satha,&nbsp;Maurice François Gonon,&nbsp;Hamid Satha","doi":"10.1007/s41779-025-01176-1","DOIUrl":null,"url":null,"abstract":"<div><p>In this paper we investigate the impact of ZrO<sub>2</sub> and TiO<sub>2</sub> as nucleating agents on the crystallization behavior of a lithium aluminosilicate (LAS) glass–ceramic (G-C). The crystallization mechanism is explored at first through X-ray diffraction analyses next to various heat treatments. Differential scanning calorimetry (DSC) analyses conducted under non-isothermal conditions at different heating rates reveal well-defined exothermic peaks. The activation energy (<i>Ea</i>), the key parameter in understanding thermal kinetics, is determined through model-free methods, specifically Flynn Wall Ozawa (FWO) and Kissinger Akahira Sunose (KAS), as well as the model-fitting approach (Coats-Redfern, C–R method). Additionally, the crystallization mechanism of the studied LAS glass ceramic is discussed utilizing the C–R method and Criado’s methods. By employing these techniques, a comprehensive analysis of the LAS glass–ceramic system is provided, contributing to the fundamental understanding of its crystallization processes, and laying the groundwork for further advancements in G–C materials.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 4","pages":"1417 - 1430"},"PeriodicalIF":2.1000,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Australian Ceramic Society","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s41779-025-01176-1","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0

Abstract

In this paper we investigate the impact of ZrO2 and TiO2 as nucleating agents on the crystallization behavior of a lithium aluminosilicate (LAS) glass–ceramic (G-C). The crystallization mechanism is explored at first through X-ray diffraction analyses next to various heat treatments. Differential scanning calorimetry (DSC) analyses conducted under non-isothermal conditions at different heating rates reveal well-defined exothermic peaks. The activation energy (Ea), the key parameter in understanding thermal kinetics, is determined through model-free methods, specifically Flynn Wall Ozawa (FWO) and Kissinger Akahira Sunose (KAS), as well as the model-fitting approach (Coats-Redfern, C–R method). Additionally, the crystallization mechanism of the studied LAS glass ceramic is discussed utilizing the C–R method and Criado’s methods. By employing these techniques, a comprehensive analysis of the LAS glass–ceramic system is provided, contributing to the fundamental understanding of its crystallization processes, and laying the groundwork for further advancements in G–C materials.

用非等温模型表征SiO₂-Al₂O₃-Li₂O玻璃陶瓷及其结晶机理
本文研究了ZrO2和TiO2作为成核剂对硅酸铝锂(LAS)玻璃陶瓷(G-C)结晶行为的影响。首先通过x射线衍射分析和各种热处理来探讨结晶机理。差示扫描量热法(DSC)分析在不同加热速率下进行的非等温条件下显示明确的放热峰。活化能(Ea)是理解热动力学的关键参数,通过无模型方法确定,特别是Flynn Wall Ozawa (FWO)和Kissinger Akahira Sunose (KAS),以及模型拟合方法(Coats-Redfern, C-R方法)。此外,利用C-R法和Criado的方法讨论了所研究的LAS玻璃陶瓷的结晶机理。通过使用这些技术,提供了LAS玻璃陶瓷系统的全面分析,有助于对其结晶过程的基本理解,并为G-C材料的进一步发展奠定了基础。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Journal of the Australian Ceramic Society
Journal of the Australian Ceramic Society Materials Science-Materials Chemistry
CiteScore
3.70
自引率
5.30%
发文量
123
期刊介绍: Publishes high quality research and technical papers in all areas of ceramic and related materials Spans the broad and growing fields of ceramic technology, material science and bioceramics Chronicles new advances in ceramic materials, manufacturing processes and applications Journal of the Australian Ceramic Society since 1965 Professional language editing service is available through our affiliates Nature Research Editing Service and American Journal Experts at the author''s cost and does not guarantee that the manuscript will be reviewed or accepted
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信