Abdelheq Layachi, Soufyane Satha, Maurice François Gonon, Hamid Satha
{"title":"Characterization and crystallization mechanism of SiO₂-Al₂O₃-Li₂O glass–ceramic using non-isothermal models","authors":"Abdelheq Layachi, Soufyane Satha, Maurice François Gonon, Hamid Satha","doi":"10.1007/s41779-025-01176-1","DOIUrl":null,"url":null,"abstract":"<div><p>In this paper we investigate the impact of ZrO<sub>2</sub> and TiO<sub>2</sub> as nucleating agents on the crystallization behavior of a lithium aluminosilicate (LAS) glass–ceramic (G-C). The crystallization mechanism is explored at first through X-ray diffraction analyses next to various heat treatments. Differential scanning calorimetry (DSC) analyses conducted under non-isothermal conditions at different heating rates reveal well-defined exothermic peaks. The activation energy (<i>Ea</i>), the key parameter in understanding thermal kinetics, is determined through model-free methods, specifically Flynn Wall Ozawa (FWO) and Kissinger Akahira Sunose (KAS), as well as the model-fitting approach (Coats-Redfern, C–R method). Additionally, the crystallization mechanism of the studied LAS glass ceramic is discussed utilizing the C–R method and Criado’s methods. By employing these techniques, a comprehensive analysis of the LAS glass–ceramic system is provided, contributing to the fundamental understanding of its crystallization processes, and laying the groundwork for further advancements in G–C materials.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 4","pages":"1417 - 1430"},"PeriodicalIF":2.1000,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Australian Ceramic Society","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s41779-025-01176-1","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0
Abstract
In this paper we investigate the impact of ZrO2 and TiO2 as nucleating agents on the crystallization behavior of a lithium aluminosilicate (LAS) glass–ceramic (G-C). The crystallization mechanism is explored at first through X-ray diffraction analyses next to various heat treatments. Differential scanning calorimetry (DSC) analyses conducted under non-isothermal conditions at different heating rates reveal well-defined exothermic peaks. The activation energy (Ea), the key parameter in understanding thermal kinetics, is determined through model-free methods, specifically Flynn Wall Ozawa (FWO) and Kissinger Akahira Sunose (KAS), as well as the model-fitting approach (Coats-Redfern, C–R method). Additionally, the crystallization mechanism of the studied LAS glass ceramic is discussed utilizing the C–R method and Criado’s methods. By employing these techniques, a comprehensive analysis of the LAS glass–ceramic system is provided, contributing to the fundamental understanding of its crystallization processes, and laying the groundwork for further advancements in G–C materials.
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