Molecular engineering of buckybowl trichalcogenasumanene toward centimeter-sized organic single-crystal arrays and devices

IF 7.4 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Hongsong Liu, Xinzi Tian, Shitao Wang, Cong Zhang, Guangxin Sun, Cheng Jiang, Beibei Fu, Ziyang Zhang, Xiangfeng Shao, Rongjin Li
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引用次数: 0

Abstract

Organic semiconductor single-crystal (OSSC) arrays, with superior charge transport and well-aligned properties, are emerging as a fascinating platform for high-performance integrated electronic and optoelectronic applications. Taking advantage of the solution processability of organic semiconductors, solution self-assembly OSSC arrays hold great potential for achieving cost-effective manufacturing of large-area and flexible electronics. While the rational design of molecular building blocks for regulating crystal growth has been achieved, the fundamental principles of molecular structure design for one-dimensional (1D) crystalline nanostructures and the impact of intermolecular interactions in molecular self-assembly remain unclear, limiting the practical application of the solution self-assembly. Drawing inspiration from the concave-convex packing preferences of bowl-shaped polyaromatic hydrocarbons, we propose an innovative molecular engineering strategy for hetero-buckybowl trichalcogenasumanenes to direct the self-assembly of OSSC arrays. The distinctive molecular architecture of trichalcogenasumanenes promotes the formation of 1D crystal arrays via directional concave-convex π-π interactions while effectively suppressing intercolumnar coupling, enhancing structural anisotropy and charge transport properties. Accordingly, the centimeter-sized OSSC arrays are obtained on various substrates via solution self-assembly. Furthermore, high-performance organic field-effect transistors (OFETs) based on these OSSC arrays demonstrate mobility values up to 0.89 cm2 V−1 s−1 with small device-to-device variation, superior to previous buckybowl-based devices. This molecular engineering strategy significantly enhances crystallinity and uniformity, providing a pathway for high-performance, large-area organic electronics.

面向厘米级有机单晶阵列和器件的巴基碗式三卤萘烯分子工程
有机半导体单晶(OSSC)阵列具有优越的电荷传输和良好的排列特性,正在成为高性能集成电子和光电子应用的迷人平台。利用有机半导体的溶液可加工性,溶液自组装OSSC阵列在实现大面积柔性电子器件的成本效益制造方面具有巨大潜力。虽然调节晶体生长的分子构建块的合理设计已经实现,但一维(1D)晶体纳米结构分子结构设计的基本原理以及分子间相互作用对分子自组装的影响尚不清楚,限制了溶液自组装的实际应用。从碗形多芳烃的凹凸填充偏好中获得灵感,我们提出了一种创新的分子工程策略来指导OSSC阵列的自组装。独特的分子结构通过定向凹凸π-π相互作用促进了一维晶体阵列的形成,同时有效地抑制了柱间耦合,增强了结构各向异性和电荷输运性质。因此,通过溶液自组装可以在各种衬底上获得厘米尺寸的OSSC阵列。此外,基于这些OSSC阵列的高性能有机场效应晶体管(ofet)的迁移率值高达0.89 cm2 V−1 s−1,器件之间的变化很小,优于以前基于buckybowl的器件。这种分子工程策略显著提高了结晶度和均匀性,为高性能、大面积有机电子学提供了途径。
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来源期刊
Science China Materials
Science China Materials Materials Science-General Materials Science
CiteScore
11.40
自引率
7.40%
发文量
949
期刊介绍: Science China Materials (SCM) is a globally peer-reviewed journal that covers all facets of materials science. It is supervised by the Chinese Academy of Sciences and co-sponsored by the Chinese Academy of Sciences and the National Natural Science Foundation of China. The journal is jointly published monthly in both printed and electronic forms by Science China Press and Springer. The aim of SCM is to encourage communication of high-quality, innovative research results at the cutting-edge interface of materials science with chemistry, physics, biology, and engineering. It focuses on breakthroughs from around the world and aims to become a world-leading academic journal for materials science.
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