Development of Alginate Beads Infused With Divalent and Trivalent Desiccant Salts for Dehumidification and Air Purification Applications

IF 2.8 3区 化学 Q2 POLYMER SCIENCE
Aindrila Bose, Juri Sonowal, R. Anandalakshmi
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Abstract

This research investigates an alternative approach to conventional methods of dehumidification to reduce the consumption of electricity and its negative impact on the environment. Alternative methods such as chemical dehumidification using desiccant materials were found to be highly effective. Due to the limitations of the currently used solid and liquid desiccants, biopolymer beads could be used as an effective solution. In this study, spherical beads were developed using sodium alginate, a non-toxic biopolymer, and desiccant salts were incorporated by ion-induced gelation. Three different salt combinations in various concentrations were tested and optimized, and six were selected among them for further characterization and assay. Fourier transform infrared spectroscopy studies confirmed the bond formation of these cations with COO groups of alginate. High moisture absorption rates of zinc–magnesium 15% (ZM15) and zinc–aluminum 15% (ZA15) samples at 78.5% and 67.8%, respectively, were observed. The maximum regeneration temperature of the ZM15 sample was determined as 66.8°C from thermogravimetric analysis, which is in the range of currently used liquid desiccant materials. Antibacterial activity tests showed promising results for all the experimented samples with prominent inhibition zones. These findings indicate that the developed beads are suitable for utilization in air dehumidification and purification systems.

Abstract Image

海藻酸盐注入二价和三价干燥剂用于除湿和空气净化的研制
本研究调查了一种替代传统除湿方法的方法,以减少电力消耗及其对环境的负面影响。替代方法,如使用干燥剂材料的化学除湿被发现是非常有效的。由于目前使用的固体和液体干燥剂的局限性,生物聚合物珠可以作为一种有效的解决方案。在本研究中,用海藻酸钠(一种无毒的生物聚合物)制成球形珠子,并用离子诱导凝胶法加入干燥剂盐。对三种不同浓度的盐组合进行了测试和优化,并从中选择了六种盐组合进行进一步的表征和分析。傅里叶变换红外光谱研究证实了这些阳离子与海藻酸盐的COO−基团成键。锌镁15% (ZM15)和锌铝15% (ZA15)的吸湿率分别为78.5%和67.8%。热重分析确定ZM15样品的最高再生温度为66.8℃,在目前使用的液体干燥剂范围内。抑菌活性试验结果表明,所有实验样品均具有明显的抑菌带。研究结果表明,所研制的微球适用于空气除湿净化系统。
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来源期刊
Journal of Applied Polymer Science
Journal of Applied Polymer Science 化学-高分子科学
CiteScore
5.70
自引率
10.00%
发文量
1280
审稿时长
2.7 months
期刊介绍: The Journal of Applied Polymer Science is the largest peer-reviewed publication in polymers, #3 by total citations, and features results with real-world impact on membranes, polysaccharides, and much more.
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