Ultrafast Kinetics of 4-Nitrophenol Reduction via Coral-Like Nanostructured Cu Mesh Monitored By Real-Time UV–Vis Absorption Spectroscopy

IF 3.2 4区 工程技术 Q2 CHEMISTRY, MULTIDISCIPLINARY
Min Gyu Lee, Younghun Kim
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Abstract

Analyzing ultrafast liquid-phase reactions in real time presents significant challenges owing to their rapid kinetics. In this study, by employing the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) as a model reaction, we demonstrate the feasibility of real-time kinetic analysis using UV–Vis absorption spectroscopy. This reaction, which was completed within 10 s, was successfully monitored and analyzed to understand the limitations of conventional ultrafast reaction methods and explore steps to overcome them. A novel coral-like ultrasonic-treated Cu (UCu) mesh fabricated via sulfidation and ultrasonic treatments was utilized as the catalyst for this reaction, resulting in a high specific surface area and abundant active sites. The UCu mesh exhibited an apparent rate constant of 0.353 s−1, significantly outperforming other reported catalysts, such as ZnO@Cu (0.043 s−1) and Cu nanowires (0.076 s−1). Compared to Cu and CuS meshes, the UCu mesh demonstrated a 29- to 58-fold improvement in catalytic performance under identical conditions. These results demonstrate the effectiveness of integrating real-time UV–Vis spectroscopy with advanced nanostructured catalysts for ultrafast reaction analyses. This study establishes the UCu mesh as a highly efficient and reusable catalyst with promising applications in environmental and industrial processes requiring rapid catalytic reactions.

Abstract Image

Abstract Image

实时紫外可见吸收光谱监测珊瑚样纳米结构铜网还原4-硝基苯酚的超快动力学
由于超快液相反应的快速动力学,对其进行实时分析提出了重大挑战。本研究以4-硝基苯酚(4-NP)还原为4-氨基苯酚(4-AP)为模型反应,验证了利用紫外可见吸收光谱进行实时动力学分析的可行性。该反应在10 s内完成,通过对其进行成功的监测和分析,了解了传统超快反应方法的局限性,并探索了克服这些局限性的步骤。利用一种新型的珊瑚状超声处理Cu (UCu)网作为催化剂,通过硫化和超声处理制备了该反应,从而获得了高比表面积和丰富的活性位点。UCu网的表观速率常数为0.353 s−1,明显优于其他催化剂,如ZnO@Cu (0.043 s−1)和Cu纳米线(0.076 s−1)。与Cu网和Cu网相比,在相同条件下,UCu网的催化性能提高了29- 58倍。这些结果证明了将实时紫外可见光谱与先进纳米结构催化剂相结合用于超快反应分析的有效性。本研究确定了UCu网作为一种高效、可重复使用的催化剂,在需要快速催化反应的环境和工业过程中具有广阔的应用前景。
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来源期刊
Korean Journal of Chemical Engineering
Korean Journal of Chemical Engineering 工程技术-工程:化工
CiteScore
4.60
自引率
11.10%
发文量
310
审稿时长
4.7 months
期刊介绍: The Korean Journal of Chemical Engineering provides a global forum for the dissemination of research in chemical engineering. The Journal publishes significant research results obtained in the Asia-Pacific region, and simultaneously introduces recent technical progress made in other areas of the world to this region. Submitted research papers must be of potential industrial significance and specifically concerned with chemical engineering. The editors will give preference to papers having a clearly stated practical scope and applicability in the areas of chemical engineering, and to those where new theoretical concepts are supported by new experimental details. The Journal also regularly publishes featured reviews on emerging and industrially important subjects of chemical engineering as well as selected papers presented at international conferences on the subjects.
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