Preparation of new coal gangue-based cementitious material via hydrothermal synthesis–low temperature calcination method

IF 3.9 3区 工程技术 Q2 CONSTRUCTION & BUILDING TECHNOLOGY
Tingye Qi, Lubin Li, Junjie He, Guorui Feng, Linfei Wang, Hongtao Xu, Tian Qiu, Siyuan Cheng, Xinkai Qi, Kexin Xu
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Abstract

Traditional cement-based materials’ economic and environmental concerns urge low-carbon alternatives. This study activates coal gangue via hydrothermal synthesis − low temperature calcination to explore optimal activation conditions for cement substitution. A Box-Behnken response surface experiment was designed with 28d compressive strength as the response index to study the effects of hydrothermal temperature, Ca/Si ratio, NaOH concentration, and calcination temperature on coal gangue-based cementitious materials. Single-factor optimization was conducted based on significant factors identified via response surface analysis. Phase evolution and hydration mechanisms were analyzed using XRD, SEM, TG-DSC, etc. Results indicated that optimal conditions were 90 °C, Ca/Si = 2.0, NaOH = 1.5%, and 800 °C, with the Ca/Si ratio and calcination temperature exerting the most significant impact, achieving a 28d compressive strength of 20.1 MPa. At Ca/Si = 2.0, the highest content of C12A7 was found in the clinker. The formation of β-C2S and α’H-C2S at 800 °C facilitated the densification of C–S–H with ettringite. Hydrothermal pre-treatment lowered the C2S synthesis temperature by 200 °C and enhanced the 28d compressive strength to 191% of that obtained using the one-step calcination method. The results provide theoretical support for the utilization of coal gangue as a cementitious material, promoting its sustainable resource utilization.

Abstract Image

Abstract Image

水热合成-低温煅烧法制备新型煤矸石基胶凝材料
传统水泥基材料的经济和环境问题促使人们选择低碳替代品。本研究通过水热合成-低温煅烧对煤矸石进行活化,探索替代水泥的最佳活化条件。设计Box-Behnken响应面实验,以28d抗压强度为响应指标,研究水热温度、Ca/Si比、NaOH浓度、煅烧温度对煤矸石基胶凝材料的影响。在响应面分析确定显著因素的基础上进行单因素优化。采用XRD、SEM、TG-DSC等分析了相演化和水化机理。结果表明,最佳工艺条件为90℃、Ca/Si = 2.0、NaOH = 1.5%、800℃,其中Ca/Si比和煅烧温度影响最大,可获得28d抗压强度为20.1 MPa。当Ca/Si = 2.0时,熟料中C12A7含量最高。800℃时β-C2S和α′H-C2S的形成促进了C - s - h与钙矾石的致密化。水热预处理使C2S合成温度降低200℃,28d抗压强度提高到一步煅烧法的191%。研究结果为利用煤矸石作为胶凝材料,促进煤矸石资源的可持续利用提供了理论支持。
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来源期刊
Materials and Structures
Materials and Structures 工程技术-材料科学:综合
CiteScore
6.40
自引率
7.90%
发文量
222
审稿时长
5.9 months
期刊介绍: Materials and Structures, the flagship publication of the International Union of Laboratories and Experts in Construction Materials, Systems and Structures (RILEM), provides a unique international and interdisciplinary forum for new research findings on the performance of construction materials. A leader in cutting-edge research, the journal is dedicated to the publication of high quality papers examining the fundamental properties of building materials, their characterization and processing techniques, modeling, standardization of test methods, and the application of research results in building and civil engineering. Materials and Structures also publishes comprehensive reports prepared by the RILEM’s technical committees.
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