Taguchi based optimisation of mix design parameters for M60 Grade GGBS-dolomite based geopolymer concrete

IF 5.8 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Najeeb Manhanpally , Praveen Nagarajan , Suman Saha , Sudha Das , Blessen Skariah Thomas , Thandiwe Sithole
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Abstract

Geopolymer concrete (GPC) has emerged as a sustainable alternative to Portland cement concrete with reduced CO2 emissions per tonne of concrete. However, its mix design is complex due to multiple interrelated factors such as binder content, binder proportion, alkaline activator to binder ratio (AAS/B), sodium silicate to sodium hydroxide ratio (SS/SH), and NaOH molarity, often requiring numerous trial mixes. This complexity makes the process time-consuming and a barrier to its widespread adoption. This study presents a systematic approach to optimise high-strength (M60 grade) GPC using slag and dolomite as binders under ambient curing conditions. The Taguchi method was used to evaluate five mix parameters at four levels each, reducing the number of experimental trials from 1024 (factorial design) to just 16. The results showed that binder proportion, AAS/B ratio, and NaOH molarity significantly affect both compressive strength and workability. AAS/B ratio was most influential on workability, while binder proportion critically influenced strength. The optimised mix—430 kg/m3 binder, 80:20 GGBS:dolomite, AAS/B = 0.45, SS/SH = 2, and 10 M NaOH—achieved a 28-day compressive strength of 71.10 N/mm2. A regression model is developed using standardised data to predict compressive strength for high strength slag-dolomite based geopolymer concrete, which yielded a high predictive accuracy (R2 = 0.94, RMSE = 2.01 N/mm2, MAE = 1.577 N/mm2). The novelty of this work lies in combining GGBS and dolomite in ambient-cured GPC, guided by a robust statistical framework. The Taguchi method is effective in simplifying the optimisation process, offering a cost-efficient, less labour-intensive, and reproducible strategy for mix design in complex geopolymer systems.

Abstract Image

基于田口的M60级ggbs -白云石基地聚合物混凝土配合比设计参数优化
地聚合物混凝土(GPC)已成为波特兰水泥混凝土的可持续替代品,每吨混凝土的二氧化碳排放量减少。然而,由于多种相互关联的因素,如粘合剂含量、粘合剂比例、碱性活化剂与粘合剂比(AAS/B)、水玻璃与氢氧化钠比(SS/SH)、NaOH摩尔浓度等,其配合比设计非常复杂,往往需要多次试验配合比。这种复杂性使得该过程非常耗时,并成为其广泛采用的障碍。本研究提出了一种系统的方法来优化高强度(M60级)GPC使用渣和白云石作为粘合剂在室温固化条件下。使用田口法在每个水平上评估五个混合参数,将实验试验的数量从1024个(析因设计)减少到16个。结果表明,粘结剂配比、AAS/B比和NaOH摩尔浓度对材料的抗压强度和和易性均有显著影响。AAS/B比对和易性影响最大,粘结剂比对强度影响最大。优化后的混合物——粘合剂430 kg/m3, GGBS:白云石80:20,AAS/B = 0.45, SS/SH = 2, 10 M naoh——28天抗压强度为71.10 N/mm2。利用标准化数据建立回归模型,预测高强度矿渣白云石基地聚合物混凝土的抗压强度,预测精度较高(R2 = 0.94, RMSE = 2.01 N/mm2, MAE = 1.577 N/mm2)。这项工作的新颖之处在于在一个强大的统计框架的指导下,将GGBS和白云石结合在环境固化的GPC中。田口方法有效地简化了优化过程,为复杂地聚合物体系的混合设计提供了一种成本效益高、劳动强度低、可重复的策略。
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来源期刊
Sustainable Chemistry and Pharmacy
Sustainable Chemistry and Pharmacy Environmental Science-Pollution
CiteScore
8.20
自引率
6.70%
发文量
274
审稿时长
37 days
期刊介绍: Sustainable Chemistry and Pharmacy publishes research that is related to chemistry, pharmacy and sustainability science in a forward oriented manner. It provides a unique forum for the publication of innovative research on the intersection and overlap of chemistry and pharmacy on the one hand and sustainability on the other hand. This includes contributions related to increasing sustainability of chemistry and pharmaceutical science and industries itself as well as their products in relation to the contribution of these to sustainability itself. As an interdisciplinary and transdisciplinary journal it addresses all sustainability related issues along the life cycle of chemical and pharmaceutical products form resource related topics until the end of life of products. This includes not only natural science based approaches and issues but also from humanities, social science and economics as far as they are dealing with sustainability related to chemistry and pharmacy. Sustainable Chemistry and Pharmacy aims at bridging between disciplines as well as developing and developed countries.
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