Jialin Li , Fan Zhang , Jin Guo , Zelong Wu , Binhua Wu
{"title":"Study on the deflagrations of H2/air in a 1-m3 vessel with a hinged aluminum vent panel: Effects of hydrogen concentration and ignition position","authors":"Jialin Li , Fan Zhang , Jin Guo , Zelong Wu , Binhua Wu","doi":"10.1016/j.jlp.2025.105763","DOIUrl":null,"url":null,"abstract":"<div><div>The effects of ignition position and hydrogen concentration on the pressure build-up and flame evolution during H<sub>2</sub>/air deflagrations were studied in a 1-m<sup>3</sup> vessel with hinged aluminum vent panel. Three ignition positions were tested: TI (top ignition), CI (central ignition), and BI (bottom ignition), with hydrogen concentrations ranging from 12 vol% to 27 vol%. Explosion overpressure was simulated using the CFD software FLACS and validated against experimental data. Results revealed that Helmholtz oscillations occurred only for 12–18 vol% H<sub>2</sub>/air mixtures at TI. Three overpressure peaks inside the vessel were identified: <em>P</em><sub><em>1</em></sub>, <em>P</em><sub><em>2</em></sub>, and <em>P</em><sub><em>vib</em></sub>, caused by the opening of the aluminum panel, interplay between the external explosion and the venting process, and flame-acoustic oscillations, respectively. Compared to inertia-free venting, the aluminum panel significantly increased <em>P</em><sub><em>1</em></sub> at TI. For CI, the panel enhances the external explosion, but it weakens the explosion at BI. When hydrogen concentration exceeded 18 vol%, the maximum explosion overpressure (<em>P</em><sub><em>max</em></sub>) at all ignition positions increased with increasing hydrogen concentration. An external overpressure peak, <em>P</em><sub><em>ext</em></sub>, was observed at all ignition positions for hydrogen concentration above 18 vol%. For TI, an additional overpressure peak, <em>P</em><sub><em>open</em></sub>, caused by the propagation of the flame wave after the aluminum panel opening, was recorded. The maximum external overpressure (<em>P</em><sub><em>e-max</em></sub>) increased with hydrogen concentration. The simulated values of <em>P</em><sub><em>max</em></sub> and <em>P</em><sub><em>e-max</em></sub> closely matched the experimental data for CI. However, simulations overestimated the experimental results for hydrogen concentration above 18 vol% at TI and BI. Additionally, the vent panel obstructed external flame propagation.</div></div>","PeriodicalId":16291,"journal":{"name":"Journal of Loss Prevention in The Process Industries","volume":"98 ","pages":"Article 105763"},"PeriodicalIF":4.2000,"publicationDate":"2025-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Loss Prevention in The Process Industries","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0950423025002219","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The effects of ignition position and hydrogen concentration on the pressure build-up and flame evolution during H2/air deflagrations were studied in a 1-m3 vessel with hinged aluminum vent panel. Three ignition positions were tested: TI (top ignition), CI (central ignition), and BI (bottom ignition), with hydrogen concentrations ranging from 12 vol% to 27 vol%. Explosion overpressure was simulated using the CFD software FLACS and validated against experimental data. Results revealed that Helmholtz oscillations occurred only for 12–18 vol% H2/air mixtures at TI. Three overpressure peaks inside the vessel were identified: P1, P2, and Pvib, caused by the opening of the aluminum panel, interplay between the external explosion and the venting process, and flame-acoustic oscillations, respectively. Compared to inertia-free venting, the aluminum panel significantly increased P1 at TI. For CI, the panel enhances the external explosion, but it weakens the explosion at BI. When hydrogen concentration exceeded 18 vol%, the maximum explosion overpressure (Pmax) at all ignition positions increased with increasing hydrogen concentration. An external overpressure peak, Pext, was observed at all ignition positions for hydrogen concentration above 18 vol%. For TI, an additional overpressure peak, Popen, caused by the propagation of the flame wave after the aluminum panel opening, was recorded. The maximum external overpressure (Pe-max) increased with hydrogen concentration. The simulated values of Pmax and Pe-max closely matched the experimental data for CI. However, simulations overestimated the experimental results for hydrogen concentration above 18 vol% at TI and BI. Additionally, the vent panel obstructed external flame propagation.
期刊介绍:
The broad scope of the journal is process safety. Process safety is defined as the prevention and mitigation of process-related injuries and damage arising from process incidents involving fire, explosion and toxic release. Such undesired events occur in the process industries during the use, storage, manufacture, handling, and transportation of highly hazardous chemicals.