Multifunctional bimetallic MOF engineering: Innovative synthesis and versatile applications in adsorption, catalysis, sensing, and energy

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews Pub Date : 2025-08-27 DOI:10.1016/j.ccr.2025.217114

Hong Wang , Liang Yang , Yanning Yang , Liangsheng Jia

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引用次数: 0

Abstract

With the growing demand for high-performance materials in modern society, bimetallic metal-organic frameworks (BMOFs) have emerged as a novel class of porous crystalline materials, demonstrating remarkable potential across diverse fields due to their unique physicochemical properties and broad application prospects. By incorporating a secondary metal center or mixed-metal nodes, BMOFs not only retain the advantages of conventional MOFs but also exhibit enhanced performance and functional diversity. This review comprehensively summarizes the fundamental characteristics of BMOFs, including high porosity, large specific surface area, excellent thermal/chemical stability, abundant active sites, superior conductivity, and tunable composition/structure. Moreover, we critically discuss the synthesis strategies of BMOFs, such as one-pot synthesis, ion exchange, template-assisted methods, and other innovative approaches. Furthermore, the recent advancements in BMOFs for adsorption, catalysis, sensing, and energy-related applications are thoroughly reviewed. Finally, we outline the current challenges and future research directions, emphasizing the importance of optimizing synthesis strategies, expanding application scopes, and establishing sustainable systems. This review aims to provide both theoretical insights and practical guidance for the design and application of BMOFs and their derived materials.

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多功能双金属MOF工程：在吸附、催化、传感、能源等领域的创新合成和广泛应用

随着现代社会对高性能材料需求的不断增长，双金属金属有机骨架（BMOFs）作为一类新型多孔晶体材料，以其独特的物理化学性质和广阔的应用前景，在各个领域显示出巨大的潜力。通过加入二次金属中心或混合金属节点，BMOFs不仅保留了传统MOFs的优点，而且性能和功能多样性也得到了提高。本文综述了BMOFs的基本特性，包括高孔隙率、大比表面积、优异的热/化学稳定性、丰富的活性位点、优越的导电性和可调的组成/结构。此外，我们批判性地讨论了BMOFs的合成策略，如一锅合成、离子交换、模板辅助方法和其他创新方法。此外，对BMOFs在吸附、催化、传感和能源相关应用方面的最新进展进行了综述。最后，提出了当前面临的挑战和未来的研究方向，强调了优化综合策略、扩大应用范围和建立可持续发展体系的重要性。本文旨在为BMOFs及其衍生材料的设计和应用提供理论见解和实践指导。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Coordination Chemistry Reviews 化学-无机化学与核化学

CiteScore

34.30

自引率

5.30%

发文量

457

审稿时长

54 days

期刊介绍： Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers. The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.