Raman spectroscopic study on solute–solvent interactions in saturated 2,2’-bipyridine and benzene solution

Abstract

Raman scattering measurements are performed on the pure benzene (B), 2,2’-bipyridine (BD), and the saturated BD-B solution at 295 and 80 K to investigate the solute–solvent interaction on the vibrational properties. The spectrum of the BD-B shows almost a simply addition of the individual spectra of BD and B, suggesting no strong interaction among BD and B molecules. At low temperature, the solution crystallizes and its spectrum shows obvious changes including the inter- and intramolecular modes, especially the modes associated with the lattice vibrations, C–H in-plane bending, C–C interring stretching, and high-frequency C–H stretching. Our work contributes to understand the interaction between organic solute and solvent.