High-Efficiency Removal of Silica and Alumina from Rough Concentrate of Refractory Oolitic Hematite Ore via High-Pressure Alkaline and Acid-Leaching Process

IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
JOM Pub Date : 2025-07-25 DOI:10.1007/s11837-025-07574-x
Mengjie Hu, Deqing Zhu, Jian Pan, Zhengqi Guo, Congcong Yang, Siwei Li, Wen Cao
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Abstract

Despite the abundant reserves of high-phosphorus oolitic iron ore, its complex mineral structure, ultrafine crystal grains, and elevated phosphorus content render conventional beneficiation techniques ineffective for the deep removal of silicon, aluminum, and phosphorus impurities. This study innovatively proposes a synergistic impurity removal process that combines high-pressure alkaline leaching with acid leaching. Compared with conventional alkaline leaching, the high-pressure leaching process has significant advantages: the leaching duration decreases from 60 min to 20 min, the NaOH consumption decreases from 300 kg/t to 200 kg/t, the iron concentration increases from 58.14% to 61.95%, and the SiO2, Al2O3, and P contents decrease to 2.53%, 6.58%, and 0.052%, respectively. Mechanistic studies reveal that elevated temperature and pressure conditions significantly enhance the penetration of NaOH solution into particle interiors, where the alkaline medium selectively reacts with silicate gangue phases. This reaction disrupts the oolitic structure, exposing fresh reactive surfaces and accelerating gangue dissolution kinetics. The synergistic effects establish a three-dimensional leaching channel network on particle surfaces, providing critical thermodynamic and kinetic conditions for efficient impurity removal. These findings offer theoretical insights into the high-value utilization of similarly refractory iron ores and propose a transformative technical framework for deep impurity extraction in complex ore systems.

高压碱酸浸法高效脱除难选鲕状赤铁矿粗精矿中的二氧化硅和氧化铝
高磷鲕状铁矿储量丰富,但其矿物结构复杂、晶粒超细、磷含量高,使得常规选矿技术对硅、铝、磷等杂质的深度脱除效果不明显。本研究创新性地提出了高压碱浸与酸浸相结合的协同除杂工艺。与常规碱浸相比,高压浸出工艺具有显著优势,浸出时间由60 min缩短至20 min, NaOH用量由300 kg/t降至200 kg/t,铁浓度由58.14%提高至61.95%,SiO2、Al2O3和P含量分别降至2.53%、6.58%和0.052%。机理研究表明,升高的温度和压力条件显著增强了NaOH溶液对颗粒内部的渗透,其中碱性介质与硅酸盐脉石相选择性反应。这种反应破坏了鲕状结构,暴露出新的反应表面,加速了脉石溶解动力学。协同效应在颗粒表面建立了三维浸出通道网络,为有效去除杂质提供了关键的热力学和动力学条件。这些发现为类似难选铁矿石的高价值利用提供了理论见解,并提出了在复杂矿石系统中深层杂质提取的变革性技术框架。
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来源期刊
JOM
JOM 工程技术-材料科学:综合
CiteScore
4.50
自引率
3.80%
发文量
540
审稿时长
2.8 months
期刊介绍: JOM is a technical journal devoted to exploring the many aspects of materials science and engineering. JOM reports scholarly work that explores the state-of-the-art processing, fabrication, design, and application of metals, ceramics, plastics, composites, and other materials. In pursuing this goal, JOM strives to balance the interests of the laboratory and the marketplace by reporting academic, industrial, and government-sponsored work from around the world.
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