E. V. Chernyshova, S. N. Yudin, S. S. Yurlov, K. V. Kuskov, D. O. Moscovskikh, V. V. Khovaylo
{"title":"Thermoelectric Properties of CaMnO3 Doped with Gadolinium Ions","authors":"E. V. Chernyshova, S. N. Yudin, S. S. Yurlov, K. V. Kuskov, D. O. Moscovskikh, V. V. Khovaylo","doi":"10.1134/S2635167625600658","DOIUrl":null,"url":null,"abstract":"<p>Single-phase hollow spheres based on calcium manganite CaMnO<sub>3</sub> and gadolinium-doped Ca<sub>0.96</sub>Gd<sub>0.04</sub>MnO<sub>3</sub> with the perovskite structure <i>Pnma</i> are synthesized via the method of spray solution combustion synthesis<i>.</i> Spark plasma sintering leads to the production of a secondary phase of marokite CaMn<sub>2</sub>O<sub>4</sub> with the <i>Pbcm</i> structure, while doping promotes to decrease the marokite content. A change in the parameters of the perovskite crystal lattice is established, which indirectly indicates the substitution of Ca<sup>2+</sup> with Gd<sup>3+</sup> and the formation of oxygen vacancies: both factors lead to a change in the Mn<sup>3+</sup>/Mn<sup>4+</sup> ratio in the structure and, as a consequence, an increase in the electrical conductivity in the doped material due to a decrease in the activation energy of polaron hopping between localized states of Mn<sup>3+</sup> and Mn<sup>4+</sup>. The resulting morphology enhances phonon scattering processes, which leads to a decrease in the thermal conductivity. The combination of the above factors leads to a significant increase in the thermoelectric efficiency: for Ca<sub>0.96</sub>Gd<sub>0.04</sub>MnO<sub>3</sub> the value <i>zT</i> reaches 0.26 at <i>T</i> = 975 K, which is 117% higher than that of the undoped sample (<i>zT</i> = 0.12). This confirms the promise of the chosen approaches for creating highly efficient thermoelectric ceramics.</p>","PeriodicalId":716,"journal":{"name":"Nanotechnologies in Russia","volume":"20 3","pages":"304 - 312"},"PeriodicalIF":0.8000,"publicationDate":"2025-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanotechnologies in Russia","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S2635167625600658","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Engineering","Score":null,"Total":0}
引用次数: 0
Abstract
Single-phase hollow spheres based on calcium manganite CaMnO3 and gadolinium-doped Ca0.96Gd0.04MnO3 with the perovskite structure Pnma are synthesized via the method of spray solution combustion synthesis. Spark plasma sintering leads to the production of a secondary phase of marokite CaMn2O4 with the Pbcm structure, while doping promotes to decrease the marokite content. A change in the parameters of the perovskite crystal lattice is established, which indirectly indicates the substitution of Ca2+ with Gd3+ and the formation of oxygen vacancies: both factors lead to a change in the Mn3+/Mn4+ ratio in the structure and, as a consequence, an increase in the electrical conductivity in the doped material due to a decrease in the activation energy of polaron hopping between localized states of Mn3+ and Mn4+. The resulting morphology enhances phonon scattering processes, which leads to a decrease in the thermal conductivity. The combination of the above factors leads to a significant increase in the thermoelectric efficiency: for Ca0.96Gd0.04MnO3 the value zT reaches 0.26 at T = 975 K, which is 117% higher than that of the undoped sample (zT = 0.12). This confirms the promise of the chosen approaches for creating highly efficient thermoelectric ceramics.
期刊介绍:
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