Rutherford Backscattering Spectrometry analysis of the formation of superconducting V3Si thin films

Abstract

Vanadium silicide, V${}_3$Si, is a promising superconductor for silicon-based superconducting (SC) devices due to its compatibility with silicon substrates and its potential for integration into existing semiconductor technologies. However, to date there have been only a limited number of studies of the formation of SC V${}_3$Si thin films and the associated structural and superconducting properties. This work aims to explore the structural characteristics and SC properties of V${}_3$Si films, paving the way for the development of functional SC devices for quantum technology applications. We have investigated the formation of V${}_3$Si films by directly depositing vanadium (V) onto thermally grown SiO₂ on Si, followed by high-vacuum annealing to induce the phase transformation into V${}_3$Si. Rutherford Backscattering Spectrometry (RBS) was employed throughout the sample growth process to analyze the material composition as a function of depth using a ${}^4{\text{He}}^{+}$ ion beam. Analysis of the RBS data confirmed that the V layer fully reacted with the SiO₂ substrate to form V${}_3$Si at the interface, in addition to a vanadium oxide (VO${}_x$) layer forming atop the V${}_3$Si film. The thickness of the V${}_3$Si layer ranges from 63 to 130 nm, with annealing temperatures between 750 °C and 800 °C. A sharp SC transition was observed at T${}_c$ = 13 K in the sample annealed at 750 °C, with a narrow transition width $\left(\Delta T_c\right)\text{of}0.6\text{K}$. Initial reactive ion etching (RIE) studies yielded promising results for local removal of the (VO${}_x$) to facilitate electrical contact formation to the SC layer.