Wolfgang M. Wefers , Dominik Schmidt , Lukas W. Lehnert , Maximilian Reuter , Michael Buchwitz , Claudia Kammann , Kai Velten
{"title":"Global 20-year time series of XCO2 concentrations derived from satellite observations and interpolations to analyze XCO2 anomalies caused by wildfires","authors":"Wolfgang M. Wefers , Dominik Schmidt , Lukas W. Lehnert , Maximilian Reuter , Michael Buchwitz , Claudia Kammann , Kai Velten","doi":"10.1016/j.atmosres.2025.108408","DOIUrl":null,"url":null,"abstract":"<div><div>Accurate, long-term records of atmospheric CO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> concentrations are crucial for understanding carbon cycle dynamics and evaluating the impacts of natural and anthropogenic emissions. In this study, we present a global dataset of column-averaged CO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> concentrations (XCO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>) covering the period 2003–2022, generated using an enhanced version of the XCO2SAT+ method. This approach integrates satellite observations from four missions (ENVISAT, GOSAT, GOSAT, GOSAT-2 and OCO-2) harmonized through the EMMA v4.5 product, and applies a novel spatio-temporal interpolation algorithm to estimate monthly mean XCO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> values at 23<!--> <!-->958 locations worldwide (<span><math><mo>≈</mo></math></span>95 km grid spacing). The dataset provides XCO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> estimates over global land surfaces and adjacent coastal regions. Validation against 28 TCCON sites yielded a mean absolute error (MAE) of <span><math><mrow><mn>0</mn><mo>.</mo><mn>76</mn><mspace></mspace><mstyle><mi>p</mi><mi>p</mi><mi>m</mi></mstyle></mrow></math></span>, comparable to NOAA’s CarbonTracker model (<span><math><mrow><mi>MAE</mi><mo>=</mo><mn>0</mn><mo>.</mo><mn>71</mn><mspace></mspace><mstyle><mi>p</mi><mi>p</mi><mi>m</mi></mstyle></mrow></math></span>). The method reliably reconstructs XCO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> time series even in regions with sparse satellite coverage, while preserving spatial and seasonal variability. As a demonstration, we identify XCO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> anomalies linked to major wildfire events, including North American mega-fires in 2018 and recurring fire activity in tropical northern Africa, with localized monthly anomalies exceeding 2<!--> <!-->ppm–4<!--> <!-->ppm. Comparison with recent machine learning (ML) products confirms that the XCO2SAT+ method achieves higher accuracy across multiple TCCON sites and time frames. This semi-empirical dataset provides a valuable alternative to assimilation-based models, supporting climate research, emission monitoring, and the detection of CO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> perturbations from extreme events at high spatial and temporal resolution.</div></div>","PeriodicalId":8600,"journal":{"name":"Atmospheric Research","volume":"328 ","pages":"Article 108408"},"PeriodicalIF":4.4000,"publicationDate":"2025-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Atmospheric Research","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0169809525005009","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"METEOROLOGY & ATMOSPHERIC SCIENCES","Score":null,"Total":0}
引用次数: 0
Abstract
Accurate, long-term records of atmospheric CO concentrations are crucial for understanding carbon cycle dynamics and evaluating the impacts of natural and anthropogenic emissions. In this study, we present a global dataset of column-averaged CO concentrations (XCO) covering the period 2003–2022, generated using an enhanced version of the XCO2SAT+ method. This approach integrates satellite observations from four missions (ENVISAT, GOSAT, GOSAT, GOSAT-2 and OCO-2) harmonized through the EMMA v4.5 product, and applies a novel spatio-temporal interpolation algorithm to estimate monthly mean XCO values at 23 958 locations worldwide (95 km grid spacing). The dataset provides XCO estimates over global land surfaces and adjacent coastal regions. Validation against 28 TCCON sites yielded a mean absolute error (MAE) of , comparable to NOAA’s CarbonTracker model (). The method reliably reconstructs XCO time series even in regions with sparse satellite coverage, while preserving spatial and seasonal variability. As a demonstration, we identify XCO anomalies linked to major wildfire events, including North American mega-fires in 2018 and recurring fire activity in tropical northern Africa, with localized monthly anomalies exceeding 2 ppm–4 ppm. Comparison with recent machine learning (ML) products confirms that the XCO2SAT+ method achieves higher accuracy across multiple TCCON sites and time frames. This semi-empirical dataset provides a valuable alternative to assimilation-based models, supporting climate research, emission monitoring, and the detection of CO perturbations from extreme events at high spatial and temporal resolution.
期刊介绍:
The journal publishes scientific papers (research papers, review articles, letters and notes) dealing with the part of the atmosphere where meteorological events occur. Attention is given to all processes extending from the earth surface to the tropopause, but special emphasis continues to be devoted to the physics of clouds, mesoscale meteorology and air pollution, i.e. atmospheric aerosols; microphysical processes; cloud dynamics and thermodynamics; numerical simulation, climatology, climate change and weather modification.