{"title":"Role of cathode materials and their advancement for sustainable hydrogen evolution reaction in microbial electrolysis cells","authors":"Sneha Prakash Naik , Omprakash Sarkar , Velvizhi Gokuladoss , Leonidas Matsakas , Gunda Mohanakrishna","doi":"10.1016/j.coche.2025.101176","DOIUrl":null,"url":null,"abstract":"<div><div>Microbial electrolysis cells (MECs) offers a sustainable route for hydrogen production by decarbonizing global energy demands via transformation of biogenic waste/wastewater. Leveraging microbial metabolism, MECs contribute to the waste-to-energy nexus. The efficiency of MECs is significantly influenced by selection of electrode materials such as platinum, nickel, and stainless steel, which enhance the performance through their high surface area, chemical resilience, and effective hydrogen evolution reaction. MECs have been shown to generate 853 H<sub>2</sub>/m³/d using graphite brush (anode) and Pt-loaded carbon cloth (cathode). MECs were upgraded to 1000 l, having 24 modules with 144 electrode pairs. Key features of cathode materials and its advancements used in MECs are discussed in this review.</div></div>","PeriodicalId":292,"journal":{"name":"Current Opinion in Chemical Engineering","volume":"49 ","pages":"Article 101176"},"PeriodicalIF":6.8000,"publicationDate":"2025-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Current Opinion in Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2211339825000887","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"BIOTECHNOLOGY & APPLIED MICROBIOLOGY","Score":null,"Total":0}
引用次数: 0
Abstract
Microbial electrolysis cells (MECs) offers a sustainable route for hydrogen production by decarbonizing global energy demands via transformation of biogenic waste/wastewater. Leveraging microbial metabolism, MECs contribute to the waste-to-energy nexus. The efficiency of MECs is significantly influenced by selection of electrode materials such as platinum, nickel, and stainless steel, which enhance the performance through their high surface area, chemical resilience, and effective hydrogen evolution reaction. MECs have been shown to generate 853 H2/m³/d using graphite brush (anode) and Pt-loaded carbon cloth (cathode). MECs were upgraded to 1000 l, having 24 modules with 144 electrode pairs. Key features of cathode materials and its advancements used in MECs are discussed in this review.
期刊介绍:
Current Opinion in Chemical Engineering is devoted to bringing forth short and focused review articles written by experts on current advances in different areas of chemical engineering. Only invited review articles will be published.
The goals of each review article in Current Opinion in Chemical Engineering are:
1. To acquaint the reader/researcher with the most important recent papers in the given topic.
2. To provide the reader with the views/opinions of the expert in each topic.
The reviews are short (about 2500 words or 5-10 printed pages with figures) and serve as an invaluable source of information for researchers, teachers, professionals and students. The reviews also aim to stimulate exchange of ideas among experts.
Themed sections:
Each review will focus on particular aspects of one of the following themed sections of chemical engineering:
1. Nanotechnology
2. Energy and environmental engineering
3. Biotechnology and bioprocess engineering
4. Biological engineering (covering tissue engineering, regenerative medicine, drug delivery)
5. Separation engineering (covering membrane technologies, adsorbents, desalination, distillation etc.)
6. Materials engineering (covering biomaterials, inorganic especially ceramic materials, nanostructured materials).
7. Process systems engineering
8. Reaction engineering and catalysis.