Proof of Concept Demonstration of a Flame-Resistant Structural Capacitor With Carbon Nanotube Electrodes

Prakash Giri, Brian Stuparyk, Mark J. Schulz
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Abstract

Structural capacitors are multifunctional energy storage systems that can store energy while acting as structural support. This study focuses on the demonstration of a structural capacitor fabricated using a unique combination of carbon nanotubes and fiberglass prepreg that can function at high temperatures without posing significant risk to the structure. Flat structural capacitors made by curing carbon nanotube electrodes inside glass fiber prepreg demonstrated an average capacitance of ~ 0.33–0.371 nF at 20°C. The capacitors remained operational after exposure to a high-temperature propane torch and demonstrated compliance with the ASTM D6413/D6413M-22 flammability standard. Scaling up of the size of the capacitors to form structural components of aircraft and automobiles can raise the capacitance value to store a significant amount of energy. The structural capacitor will not only enable the aircraft and automobiles to store energy, but will also shield them from electromagnetic interference, allow them endure high temperatures, and provide a strong yet lightweight structural support. Besides, a capacitor can also provide structural health monitoring in real time. This study evaluates the performance of a high-temperature capacitor utilizing fiberglass prepreg as both the dielectric and structural material, with carbon nanotube (CNT) sheets as electrodes. While fiberglass prepreg is widely available, the difficulty of scaling up CNT synthesis has been a major limitation in practical applications. This study also aims to overcome this barrier by presenting a feasible approach for producing CNT sheets at an industrially relevant scale, facilitating their integration into multifunctional structural-electronic components.

Abstract Image

碳纳米管电极耐燃结构电容器的概念验证
结构电容器是一种既能储存能量又能起到结构支撑作用的多功能储能系统。本研究的重点是展示一种结构电容器,该电容器使用碳纳米管和玻璃纤维预浸料的独特组合制造,可以在高温下工作而不会对结构造成重大风险。在玻璃纤维预浸料内固化碳纳米管电极制成的扁平结构电容器在20℃时的平均电容为~ 0.33-0.371 nF。这些电容器在暴露于高温丙烷炬下后仍能工作,并证明符合ASTM D6413/D6413M-22可燃性标准。扩大电容器的尺寸,以形成飞机和汽车的结构部件,可以提高电容值,以存储大量的能量。结构电容器不仅可以使飞机和汽车储存能量,还可以屏蔽电磁干扰,使它们能够承受高温,并提供坚固而轻便的结构支撑。此外,电容器还可以提供结构健康状况的实时监测。本研究利用玻璃纤维预浸料作为介质和结构材料,以碳纳米管(CNT)片作为电极,评估了高温电容器的性能。虽然玻璃纤维预浸料广泛可用,但扩大碳纳米管合成的难度一直是实际应用的主要限制。本研究还旨在通过提出一种可行的方法,在工业相关规模上生产碳纳米管片,促进其集成到多功能结构电子元件中,从而克服这一障碍。
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