The Effect of Promoters Added on Ni Supported on Cerium–Zirconia on CO2 Activation and CO Selectivity of the RWGS Reaction

IF 2.3 4区 化学 Q3 CHEMISTRY, PHYSICAL
Camila Emilia Kozonoe, Wallisson Senna Gomes Silva, Martin Schmal
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引用次数: 0

Abstract

The main challenge for the RWGS reaction’s technological feasibility is the search for catalysts operating at low temperatures for CO2 activation and conversion and preventing secondary reactions, such as methanation. In this work, the metals Copper (Cu), Iron (Fe), Ruthenium (Ru), and Nickel (Ni) catalysts and combined metals on Cerium-Zirconia support were synthesized, characterized, and tested in the RWGS. The Fe–Ni–Cu combination was the most effective at lower temperatures (400 °C) compared to other metallic combinations 2, presenting 40% CO2 conversion (equilibrium conversion is 42%) and high selectivity of 90%, CO as the main product and considerable reduction of by-products.

Graphical Abstract

Abstract Image

Abstract Image

铈锆负载镍上添加促进剂对RWGS反应CO2活化和CO选择性的影响
RWGS反应技术可行性面临的主要挑战是寻找在低温下工作的催化剂,用于二氧化碳的活化和转化,并防止二次反应,如甲烷化。本文在RWGS中合成了铜(Cu)、铁(Fe)、钌(Ru)、镍(Ni)等金属催化剂以及铈锆载体上的组合金属,并进行了表征和测试。与其他金属组合相比,Fe-Ni-Cu组合在较低温度(400°C)下最有效2,CO2转化率为40%(平衡转化率为42%),选择性高达90%,CO为主要产物,副产物大量减少。图形抽象
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Catalysis Letters
Catalysis Letters 化学-物理化学
CiteScore
5.70
自引率
3.60%
发文量
327
审稿时长
1 months
期刊介绍: Catalysis Letters aim is the rapid publication of outstanding and high-impact original research articles in catalysis. The scope of the journal covers a broad range of topics in all fields of both applied and theoretical catalysis, including heterogeneous, homogeneous and biocatalysis. The high-quality original research articles published in Catalysis Letters are subject to rigorous peer review. Accepted papers are published online first and subsequently in print issues. All contributions must include a graphical abstract. Manuscripts should be written in English and the responsibility lies with the authors to ensure that they are grammatically and linguistically correct. Authors for whom English is not the working language are encouraged to consider using a professional language-editing service before submitting their manuscripts.
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