Electrochemical detection of hydroquinone using yttrium oxide-nafion modified glassy carbon electrodes

IF 2.4 4区 化学 Q4 ELECTROCHEMISTRY
Gloria A. Cosco-Salguero , Edgar Nagles , Johisner Penagos-Llanos , Rodrigo Segura , John Hurtado
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引用次数: 0

Abstract

In this article, we report for the first time a novel method for developing modified electrodes using only yttrium oxide and Nafion on glassy carbon (N-YOX/GCE) as well as the application of this method for detecting hydroquinone (HQ). Cyclic voltammetry (CV) and scanning electron microscopy (SEM) were used to characterize the surface and activity of N-YOX/GCE. This simple electrode showed higher selectivity for the electrooxidation of HQ than catechol, with a limit of detection of 1.0 µmol/L under acidic conditions. The utility of the sensor was tested with real samples of human urine and drinking water spiked with hydroquinone.
氧化钇修饰玻碳电极对对苯二酚的电化学检测
在本文中,我们首次报道了在玻璃碳(N-YOX/GCE)上仅使用氧化钇和钠离子制备修饰电极的新方法,以及该方法在检测对苯二酚(HQ)中的应用。利用循环伏安法(CV)和扫描电镜(SEM)对N-YOX/GCE的表面和活性进行了表征。该简单电极对HQ的电氧化选择性高于儿茶酚,在酸性条件下检测限为1.0µmol/L。该传感器的效用是用人类尿液和含有对苯二酚的饮用水的真实样本进行测试的。
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来源期刊
CiteScore
3.00
自引率
20.00%
发文量
714
审稿时长
2.6 months
期刊介绍: International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry
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