Inside Front Cover: Exactly Restricting the Phenyl Ring Rotation in Metal-Organic Framework for Ultra-Sensitive and Specific Ratiometric Fluorescent Sensing of Sarin
{"title":"Inside Front Cover: Exactly Restricting the Phenyl Ring Rotation in Metal-Organic Framework for Ultra-Sensitive and Specific Ratiometric Fluorescent Sensing of Sarin","authors":"Cong Lyu, Chuanfang Zhao, Meimei Wang, Jiawen Li, Zhenzhen Cai, Xincun Dou, Baiyi Zu","doi":"10.1002/agt2.70138","DOIUrl":null,"url":null,"abstract":"<p>A goal-oriented MOF design strategy is proposed to realize the ultra-sensitive and specific detection of sarin through the rotation restricted emission mechanism. The hydrogen bonding and hydrophobic interaction between Eu-MOF and sarin efficiently lead to a dramatic change in molecular configuration, significantly enhancing the fluorescence intensity and realizing the ratiometric detection of sarin. This strategy would provide new insights for functional sensing material exploration (e70053).\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":72127,"journal":{"name":"Aggregate (Hoboken, N.J.)","volume":"6 8","pages":""},"PeriodicalIF":13.7000,"publicationDate":"2025-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/agt2.70138","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Aggregate (Hoboken, N.J.)","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/agt2.70138","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
A goal-oriented MOF design strategy is proposed to realize the ultra-sensitive and specific detection of sarin through the rotation restricted emission mechanism. The hydrogen bonding and hydrophobic interaction between Eu-MOF and sarin efficiently lead to a dramatic change in molecular configuration, significantly enhancing the fluorescence intensity and realizing the ratiometric detection of sarin. This strategy would provide new insights for functional sensing material exploration (e70053).
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