Investigation of Efficiency of Cleaning the Surface of Gas Turbine Engine Blades from Metal Oxides Using Halide-Containing Compounds

IF 0.6 4区 化学 Q4 CHEMISTRY, APPLIED
D. D. Fomina, V. Z. Poilov
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引用次数: 0

Abstract

The nozzle blades of a gas turbine engine (GTE) are an important part of an aircraft engine. During operation, the nozzle blades are exposed to high temperatures, mechanical loads, sulfide and salt corrosion. Due to the influence of aggressive factors, carbon deposits, metal oxides and microcracks form on the surface of the blades of the gas turbine engine. To restore the performance characteristics of the blades, it is necessary to clean the surface of the blades from aluminum, titanium, tungsten, chromium, and nickel oxides. Based on the analysis of literature sources, it is shown that many detergents are not able to remove these oxides with high chemical resistance from the surface of the blades. In the article, halide-containing substances such as hydrogen fluoride gas, hydrofluoric acid, and hydrochloric acid were used to clean the blades from metal oxides. The main purpose of this work was to study the efficiency of cleaning the surface of the GTE nozzle blade with halide-containing compounds from carbon deposits and stable metal oxides of aluminum, titanium, tungsten, chromium, and nickel. The composition of the material used in the study and the analytical tools used to determine the surface composition of a sample of a GTE nozzle blade made of an alloy of the KHN54KVMTYUB brand are described. The methodology and conditions of the processes of exposure to gaseous hydrogen fluoride, hydrofluoric and hydrochloric acids are considered. The features of the effect of halide-containing substances on stable metal oxides on the sample surface have been studied. It was found that hydrogen fluoride gas reacts actively with aluminum and tungsten oxide, thereby destroying the basic structure of the oxide film. Hydrofluoric acid also reacts with the components of the KHN54KVMTUB alloy, accompanied by a thinning of the oxide layer and a decrease in the oxygen content on the surface. When cleaning with hydrochloric acid using ultrasonic treatment, depressions appeared on the surface of the blades. Thus, halide-containing reagents actively react with the surface of the KHN54KVMTUB alloy, which helps to clean the blades from the oxide layer.

Abstract Image

Abstract Image

含卤化物清除燃气涡轮发动机叶片表面金属氧化物的效率研究
燃气涡轮发动机的喷嘴叶片是航空发动机的重要部件。在操作过程中,喷嘴叶片暴露在高温、机械负荷、硫化物和盐腐蚀中。由于侵蚀因素的影响,在燃气涡轮发动机叶片表面形成积碳、金属氧化物和微裂纹。为了恢复叶片的性能特征,有必要清除叶片表面的铝、钛、钨、铬和镍的氧化物。通过对文献资料的分析,表明许多清洗剂不能去除叶片表面的这些具有高耐化学性的氧化物。在本文中,使用含卤化物的物质,如氟化氢气体、氢氟酸和盐酸来清洁叶片中的金属氧化物。本工作的主要目的是研究用含卤化物的碳沉积化合物和稳定的金属氧化物铝、钛、钨、铬和镍清洁GTE喷嘴叶片表面的效率。描述了研究中使用的材料的组成以及用于确定由KHN54KVMTYUB品牌合金制成的GTE喷嘴叶片样品表面成分的分析工具。考虑了气态氟化氢、氢氟酸和盐酸暴露过程的方法和条件。研究了含卤化物物质对样品表面稳定金属氧化物的影响特征。研究发现,氟化氢气体与氧化铝和氧化钨发生反应,破坏了氧化膜的基本结构。氢氟酸还与KHN54KVMTUB合金的组分发生反应,同时使氧化层变薄,表面氧含量降低。用超声波处理盐酸清洗时,叶片表面出现凹陷。因此,含卤化物的试剂与KHN54KVMTUB合金表面积极反应,有助于清洁叶片的氧化层。
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来源期刊
CiteScore
1.60
自引率
11.10%
发文量
63
审稿时长
2-4 weeks
期刊介绍: Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
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