{"title":"One-step synthesis of ZnO/SnO2-CNF nanocomposites for sensitive NO2 detection under UV illumination","authors":"Yan Liu , Xuebin Zhou , Zhihua Ying , Yuan Jiang","doi":"10.1016/j.chemphys.2025.112908","DOIUrl":null,"url":null,"abstract":"<div><div>Nitrogen dioxide (NO<sub>2</sub>) detection is critical for environmental and industrial safety, yet existing sensors often suffer from limited sensitivity and slow response. To address this, we report a facile one-step hydrothermal synthesis of ZnO/SnO<sub>2</sub> heterostructures via a one-step hydrothermal method using cellulose nanofiber (CNF) as a templating agent. Under UV activation, the optimized composite demonstrates a high response value of 45 toward 3 ppm NO<sub>2</sub>, along with rapid response and recovery times of 15 s and 20 s, respectively. The CNF-assisted synthesis significantly enhanced NO<sub>2</sub> sensitivity and selectivity compared to conventional methods, attributed to synergistic effects of increased surface area and interfacial charge transfer. This scalable approach enables high-performance NO<sub>2</sub> sensors for real-time monitoring.</div></div>","PeriodicalId":272,"journal":{"name":"Chemical Physics","volume":"600 ","pages":"Article 112908"},"PeriodicalIF":2.4000,"publicationDate":"2025-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Physics","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S030101042500309X","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Nitrogen dioxide (NO2) detection is critical for environmental and industrial safety, yet existing sensors often suffer from limited sensitivity and slow response. To address this, we report a facile one-step hydrothermal synthesis of ZnO/SnO2 heterostructures via a one-step hydrothermal method using cellulose nanofiber (CNF) as a templating agent. Under UV activation, the optimized composite demonstrates a high response value of 45 toward 3 ppm NO2, along with rapid response and recovery times of 15 s and 20 s, respectively. The CNF-assisted synthesis significantly enhanced NO2 sensitivity and selectivity compared to conventional methods, attributed to synergistic effects of increased surface area and interfacial charge transfer. This scalable approach enables high-performance NO2 sensors for real-time monitoring.
期刊介绍:
Chemical Physics publishes experimental and theoretical papers on all aspects of chemical physics. In this journal, experiments are related to theory, and in turn theoretical papers are related to present or future experiments. Subjects covered include: spectroscopy and molecular structure, interacting systems, relaxation phenomena, biological systems, materials, fundamental problems in molecular reactivity, molecular quantum theory and statistical mechanics. Computational chemistry studies of routine character are not appropriate for this journal.