One-step synthesis of ZnO/SnO2-CNF nanocomposites for sensitive NO2 detection under UV illumination

IF 2.4 3区 化学 Q4 CHEMISTRY, PHYSICAL
Yan Liu , Xuebin Zhou , Zhihua Ying , Yuan Jiang
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引用次数: 0

Abstract

Nitrogen dioxide (NO2) detection is critical for environmental and industrial safety, yet existing sensors often suffer from limited sensitivity and slow response. To address this, we report a facile one-step hydrothermal synthesis of ZnO/SnO2 heterostructures via a one-step hydrothermal method using cellulose nanofiber (CNF) as a templating agent. Under UV activation, the optimized composite demonstrates a high response value of 45 toward 3 ppm NO2, along with rapid response and recovery times of 15 s and 20 s, respectively. The CNF-assisted synthesis significantly enhanced NO2 sensitivity and selectivity compared to conventional methods, attributed to synergistic effects of increased surface area and interfacial charge transfer. This scalable approach enables high-performance NO2 sensors for real-time monitoring.
紫外光下一步合成ZnO/SnO2-CNF纳米复合材料用于NO2的灵敏检测
二氧化氮(NO2)的检测对环境和工业安全至关重要,但现有的传感器往往存在灵敏度有限和响应缓慢的问题。为了解决这个问题,我们报道了一种简单的一步水热合成ZnO/SnO2异质结构的方法,采用纤维素纳米纤维(CNF)作为模板剂。在紫外活化下,优化后的复合材料对3 ppm NO2的响应值高达45,响应速度快,恢复时间分别为15 s和20 s。与传统方法相比,cnf辅助合成显著提高了NO2的敏感性和选择性,这归因于增加的表面积和界面电荷转移的协同效应。这种可扩展的方法使高性能NO2传感器能够进行实时监控。
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来源期刊
Chemical Physics
Chemical Physics 化学-物理:原子、分子和化学物理
CiteScore
4.60
自引率
4.30%
发文量
278
审稿时长
39 days
期刊介绍: Chemical Physics publishes experimental and theoretical papers on all aspects of chemical physics. In this journal, experiments are related to theory, and in turn theoretical papers are related to present or future experiments. Subjects covered include: spectroscopy and molecular structure, interacting systems, relaxation phenomena, biological systems, materials, fundamental problems in molecular reactivity, molecular quantum theory and statistical mechanics. Computational chemistry studies of routine character are not appropriate for this journal.
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