Guadalupe Quirarte, Alexander J. Myers, Alexander Gourley, Craig M. Weeks, B. Reeja-Jayan, Jack Beuth, Jonathan A. Malen
{"title":"High speed thermal imaging and modeling of laser powder bed fusion manufactured WC–Ni cemented carbides","authors":"Guadalupe Quirarte, Alexander J. Myers, Alexander Gourley, Craig M. Weeks, B. Reeja-Jayan, Jack Beuth, Jonathan A. Malen","doi":"10.1016/j.addma.2025.104913","DOIUrl":null,"url":null,"abstract":"<div><div>Cemented carbides such as cemented tungsten carbide (WC) are known for their use in resilient wear-resistant applications where hardness and thermal stability are imperative. They are composed of carbide particles embedded in a metal binder. Laser Powder Bed Fusion (L-PBF) is a favorable method to form cemented carbides into complex geometries, but composites pose unique challenges relative to metals typically processed by L-PBF. Resolving the melt pool temperature distributions in L-PBF is key to understanding the underlying physics of the fusion process. Using a two-color thermal imaging method, melt pool thermal maps of WC<sub>0.83</sub>-Ni<sub>0.17</sub> were captured with linear energy densities ranging from 500–1750 J/m with and without powder. WC<sub>0.83</sub>-Ni<sub>0.17</sub> melt pools exhibit temperatures above 4000 K, which can lead to the generation of other WC phases. Compared to more common L-PBF materials such as 316L stainless steel (SS), WC<sub>0.83</sub>-Ni<sub>0.17</sub> melt pools reach higher temperatures. Our direct measurements find that the thermal conductivity of WC<sub>0.83</sub>-Ni<sub>0.17</sub> is 30 W/m-K at 300 K, which is higher than the thermal conductivity of 316L SS and suggests that other heat transfer limitations must cause the elevated melt pool temperatures. A FLOW-3D CFD model based on the composite properties was compared to both the melt pool centerline temperatures and width measurements of the samples fabricated by L-PBF. The simulations indicate that specifying the onset of fluidity is key to reproducing the high temperatures observed experimentally. Although Ni has a melting point of 1728 K, the simulations do not match experiments unless the onset of fluidity is set at the melting point of WC (3143 K). Within FLOW-3D, the onset of fluidity is controlled by the critical solid fraction, which is a uniquely important parameter for simulating composite materials.</div></div>","PeriodicalId":7172,"journal":{"name":"Additive manufacturing","volume":"110 ","pages":"Article 104913"},"PeriodicalIF":11.1000,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Additive manufacturing","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2214860425002775","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, MANUFACTURING","Score":null,"Total":0}
引用次数: 0
Abstract
Cemented carbides such as cemented tungsten carbide (WC) are known for their use in resilient wear-resistant applications where hardness and thermal stability are imperative. They are composed of carbide particles embedded in a metal binder. Laser Powder Bed Fusion (L-PBF) is a favorable method to form cemented carbides into complex geometries, but composites pose unique challenges relative to metals typically processed by L-PBF. Resolving the melt pool temperature distributions in L-PBF is key to understanding the underlying physics of the fusion process. Using a two-color thermal imaging method, melt pool thermal maps of WC0.83-Ni0.17 were captured with linear energy densities ranging from 500–1750 J/m with and without powder. WC0.83-Ni0.17 melt pools exhibit temperatures above 4000 K, which can lead to the generation of other WC phases. Compared to more common L-PBF materials such as 316L stainless steel (SS), WC0.83-Ni0.17 melt pools reach higher temperatures. Our direct measurements find that the thermal conductivity of WC0.83-Ni0.17 is 30 W/m-K at 300 K, which is higher than the thermal conductivity of 316L SS and suggests that other heat transfer limitations must cause the elevated melt pool temperatures. A FLOW-3D CFD model based on the composite properties was compared to both the melt pool centerline temperatures and width measurements of the samples fabricated by L-PBF. The simulations indicate that specifying the onset of fluidity is key to reproducing the high temperatures observed experimentally. Although Ni has a melting point of 1728 K, the simulations do not match experiments unless the onset of fluidity is set at the melting point of WC (3143 K). Within FLOW-3D, the onset of fluidity is controlled by the critical solid fraction, which is a uniquely important parameter for simulating composite materials.
期刊介绍:
Additive Manufacturing stands as a peer-reviewed journal dedicated to delivering high-quality research papers and reviews in the field of additive manufacturing, serving both academia and industry leaders. The journal's objective is to recognize the innovative essence of additive manufacturing and its diverse applications, providing a comprehensive overview of current developments and future prospects.
The transformative potential of additive manufacturing technologies in product design and manufacturing is poised to disrupt traditional approaches. In response to this paradigm shift, a distinctive and comprehensive publication outlet was essential. Additive Manufacturing fulfills this need, offering a platform for engineers, materials scientists, and practitioners across academia and various industries to document and share innovations in these evolving technologies.