Water-stable PEG2000-modified citric acid crosslinked β-CD MOF for efficient removal of tetracycline hydrochloride: synthesis, adsorption behavior, and mechanism.

IF 2.5 3区 化学 Q3 BIOCHEMISTRY & MOLECULAR BIOLOGY
Carbohydrate Research Pub Date : 2025-11-01 Epub Date: 2025-08-07 DOI:10.1016/j.carres.2025.109631
Chunlin Gou, Ziqing Weng, Xiaoshuang Dai, Jianpeng Liu, Ke Mei, Bin Sun, Neng Qiu
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引用次数: 0

Abstract

To address the ecological and health risks associated with residual tetracycline hydrochloride (TCH) in water, a green-synthesized adsorbent composed of β-cyclodextrin (β-CD), citric acid (CA), and polyethylene glycol (PEG) was developed for the effective removal of TCH from wastewater. The synthetic parameters were optimized, and the resulting PEG-CA-β-CD MOF was characterized by FT-IR, XRD, and SE. TGA analysis indicated an increase in the thermal stability. The maximum adsorption capacity of PEG-CA-β-CD MOF for TCH was 221.6 mg/g at pH = 4. Adsorption kinetics were well-described by the Elovich equation model, while the Freundlich isothermal model accurately described the equilibrium data adsorption Thermodynamic analysis revealed that the adsorption process was endothermic and spontaneous. Furthermore, the adsorbent maintained 84 % of its initial adsorption capacity after four reuse cycles. Analysis using zeta potential, FT-IR, and XPS confirmed that the possible adsorption mechanism of TCH mainly involves electrostatic interactions, hydrogen bonding, and cavity encapsulation. Finally, simulated wastewater experiments showed that PEG-CA-β-CD MOF was able to adsorb TCH efficiently even in the presence of other pollutants. Overall, due to its green synthesis process, low cost, ease of regeneration, and multi-mechanistic adsorption capability, the PEG-CA-β-CD MOF exhibits significant potential for TCH removal in wastewater treatment.

水稳定peg2000修饰柠檬酸交联β-CD MOF高效去除盐酸四环素:合成、吸附行为及机理
为解决水中残留的盐酸四环素(TCH)的生态和健康风险,研制了一种由β-环糊精(β-CD)、柠檬酸(CA)和聚乙二醇(PEG)组成的绿色合成吸附剂,用于有效去除废水中的TCH。对合成参数进行优化,并用FT-IR、XRD和SE对合成的PEG-CA-β-CD MOF进行表征。TGA分析表明热稳定性有所提高。在pH = 4时,PEG-CA-β-CD MOF对TCH的最大吸附量为221.6 mg/g。Elovich方程模型较好地描述了吸附动力学,Freundlich等温模型较准确地描述了吸附平衡数据,热力学分析表明吸附过程是吸热自发的。此外,吸附剂在重复使用4次后仍保持了84%的初始吸附容量。zeta电位、FT-IR和XPS分析证实了TCH可能的吸附机制主要包括静电相互作用、氢键和空腔封装。最后,模拟废水实验表明,即使存在其他污染物,PEG-CA-β-CD MOF也能有效吸附TCH。综上所述,PEG-CA-β-CD MOF具有绿色合成、低成本、易于再生和多机理吸附等优点,在废水处理中具有去除TCH的巨大潜力。
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来源期刊
Carbohydrate Research
Carbohydrate Research 化学-生化与分子生物学
CiteScore
5.00
自引率
3.20%
发文量
183
审稿时长
3.6 weeks
期刊介绍: Carbohydrate Research publishes reports of original research in the following areas of carbohydrate science: action of enzymes, analytical chemistry, biochemistry (biosynthesis, degradation, structural and functional biochemistry, conformation, molecular recognition, enzyme mechanisms, carbohydrate-processing enzymes, including glycosidases and glycosyltransferases), chemical synthesis, isolation of natural products, physicochemical studies, reactions and their mechanisms, the study of structures and stereochemistry, and technological aspects. Papers on polysaccharides should have a "molecular" component; that is a paper on new or modified polysaccharides should include structural information and characterization in addition to the usual studies of rheological properties and the like. A paper on a new, naturally occurring polysaccharide should include structural information, defining monosaccharide components and linkage sequence. Papers devoted wholly or partly to X-ray crystallographic studies, or to computational aspects (molecular mechanics or molecular orbital calculations, simulations via molecular dynamics), will be considered if they meet certain criteria. For computational papers the requirements are that the methods used be specified in sufficient detail to permit replication of the results, and that the conclusions be shown to have relevance to experimental observations - the authors'' own data or data from the literature. Specific directions for the presentation of X-ray data are given below under Results and "discussion".
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