{"title":"Reconfigurable Tin-Halide Perovskite Resistive Switching Memory for Reservoir Computing System in Braille Code Translator","authors":"Dohyung Kim, Hansol Park and Hui Joon Park*, ","doi":"10.1021/acsmaterialslett.5c00790","DOIUrl":null,"url":null,"abstract":"<p >Resistive switching memories (RSMs) have emerged as promising candidates for a reservoir computing (RC) system, which excels in processing temporal information. Their ability to function as either volatile or nonvolatile devices makes them ideal for reservoir and readout layers. However, conventional RSMs require separate devices for these functionalities, complicating integrated RC systems. Here, we introduce tin-halide perovskite as a switching medium and present a reconfigurable RSM with Pt/FASnI<sub>3</sub>/Ag structure that integrates volatile and nonvolatile properties by modulating switching mechanisms. Under a positive bias to the Pt electrode, the device operates in a volatile threshold-switching mode based on space-charge-limited conduction, exhibiting short-term dynamics─key features for reservoir layers. On the other hand, applying positive bias to the Ag electrode activates a nonvolatile bipolar-switching mode, driven by reversible filamentary mechanisms, with long-term potentiation and depression characteristics, suitable for readout layers. Using this reconfigurable RSM, we developed a hardware RC system for Braille code recognition.</p>","PeriodicalId":19,"journal":{"name":"ACS Materials Letters","volume":"7 7","pages":"2670–2678"},"PeriodicalIF":8.7000,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Materials Letters","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsmaterialslett.5c00790","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Resistive switching memories (RSMs) have emerged as promising candidates for a reservoir computing (RC) system, which excels in processing temporal information. Their ability to function as either volatile or nonvolatile devices makes them ideal for reservoir and readout layers. However, conventional RSMs require separate devices for these functionalities, complicating integrated RC systems. Here, we introduce tin-halide perovskite as a switching medium and present a reconfigurable RSM with Pt/FASnI3/Ag structure that integrates volatile and nonvolatile properties by modulating switching mechanisms. Under a positive bias to the Pt electrode, the device operates in a volatile threshold-switching mode based on space-charge-limited conduction, exhibiting short-term dynamics─key features for reservoir layers. On the other hand, applying positive bias to the Ag electrode activates a nonvolatile bipolar-switching mode, driven by reversible filamentary mechanisms, with long-term potentiation and depression characteristics, suitable for readout layers. Using this reconfigurable RSM, we developed a hardware RC system for Braille code recognition.
期刊介绍:
ACS Materials Letters is a journal that publishes high-quality and urgent papers at the forefront of fundamental and applied research in the field of materials science. It aims to bridge the gap between materials and other disciplines such as chemistry, engineering, and biology. The journal encourages multidisciplinary and innovative research that addresses global challenges. Papers submitted to ACS Materials Letters should clearly demonstrate the need for rapid disclosure of key results. The journal is interested in various areas including the design, synthesis, characterization, and evaluation of emerging materials, understanding the relationships between structure, property, and performance, as well as developing materials for applications in energy, environment, biomedical, electronics, and catalysis. The journal has a 2-year impact factor of 11.4 and is dedicated to publishing transformative materials research with fast processing times. The editors and staff of ACS Materials Letters actively participate in major scientific conferences and engage closely with readers and authors. The journal also maintains an active presence on social media to provide authors with greater visibility.