{"title":"Inorganic Quantum Dots: Synthetic Strategy and Environmental Applications","authors":"Yuan-Long Sun, Sushu Zhang, Hui Cai, Jingyu Wang* and Zhi-Quan Tian*, ","doi":"10.1021/acsestengg.5c00232","DOIUrl":null,"url":null,"abstract":"<p >This review comprehensively summarizes the synthetic strategies, gas sensing applications, and pollutant removal performance of inorganic quantum dots (IQDs). It highlights the recent advancements in organic-phase and aqueous-phase synthesis methods that enable precise control over IQDs size, surface chemistry, and optoelectronic properties for environmental applications. The discussion emphasizes the exceptional gas sensing performance of IQDs through surface charge modulation, fluorescence quenching mechanisms, and quantum confinement effects, thus enabling ultrasensitive detection of nitrogenous and sulfur-containing pollutants. For environment remediation, IQDs demonstrate superior photocatalytic efficiency via tailored bandgap engineering, heterojunction design, and enhanced charge separation for gaseous pollutant degradation. Further, the critical challenges of IQDs in the environmental applications have been proposed from the aspects of scalable synthesis, long-term stability under operational conditions, and toxicity assessments. Overall, this review outlines the sustainable development pathways involving eco-friendly IQDs alternatives and circular economy approaches, which provide deep insights for designing next-generation IQDs systems for environmental applications.</p>","PeriodicalId":7008,"journal":{"name":"ACS ES&T engineering","volume":"5 7","pages":"1630–1654"},"PeriodicalIF":6.7000,"publicationDate":"2025-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS ES&T engineering","FirstCategoryId":"1085","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsestengg.5c00232","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
引用次数: 0
Abstract
This review comprehensively summarizes the synthetic strategies, gas sensing applications, and pollutant removal performance of inorganic quantum dots (IQDs). It highlights the recent advancements in organic-phase and aqueous-phase synthesis methods that enable precise control over IQDs size, surface chemistry, and optoelectronic properties for environmental applications. The discussion emphasizes the exceptional gas sensing performance of IQDs through surface charge modulation, fluorescence quenching mechanisms, and quantum confinement effects, thus enabling ultrasensitive detection of nitrogenous and sulfur-containing pollutants. For environment remediation, IQDs demonstrate superior photocatalytic efficiency via tailored bandgap engineering, heterojunction design, and enhanced charge separation for gaseous pollutant degradation. Further, the critical challenges of IQDs in the environmental applications have been proposed from the aspects of scalable synthesis, long-term stability under operational conditions, and toxicity assessments. Overall, this review outlines the sustainable development pathways involving eco-friendly IQDs alternatives and circular economy approaches, which provide deep insights for designing next-generation IQDs systems for environmental applications.
期刊介绍:
ACS ES&T Engineering publishes impactful research and review articles across all realms of environmental technology and engineering, employing a rigorous peer-review process. As a specialized journal, it aims to provide an international platform for research and innovation, inviting contributions on materials technologies, processes, data analytics, and engineering systems that can effectively manage, protect, and remediate air, water, and soil quality, as well as treat wastes and recover resources.
The journal encourages research that supports informed decision-making within complex engineered systems and is grounded in mechanistic science and analytics, describing intricate environmental engineering systems. It considers papers presenting novel advancements, spanning from laboratory discovery to field-based application. However, case or demonstration studies lacking significant scientific advancements and technological innovations are not within its scope.
Contributions containing experimental and/or theoretical methods, rooted in engineering principles and integrated with knowledge from other disciplines, are welcomed.