Flash Communication: On “Ag[BArF4]” and an Expedient Synthesis of [Ag(C6H6)3][BArF4]

IF 2.9 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Organometallics Pub Date : 2025-07-31 DOI:10.1021/acs.organomet.5c00170

Alex McSkimming*,

引用次数: 0

Abstract

We describe herein a simple, scalable preparation of [Ag(C₆H₆)₃][BAr^F₄] and demonstrate its utility as a halide abstraction reagent in the preparation of a coordinately unsaturated Co²⁺ complex. We hope this report resolves the ambiguous literature surrounding putative “Ag[BAr^F₄]” and facilitates the use of this reagent by others in the synthetic community.

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闪光通信：“Ag[BArF4]”及[Ag(C6H6)3][BArF4]的便捷合成

本文描述了一种简单、可扩展的[Ag(C6H6)3][BArF4]的制备方法，并证明了其作为卤化物提取试剂在制备配位不饱和Co2+配合物中的实用性。我们希望这篇报道能够解决围绕假定的“Ag[BArF4]”的模棱两可的文献，并促进合成界其他人使用该试剂。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Organometallics 化学-无机化学与核化学

CiteScore

5.60

自引率

7.10%

发文量

382

审稿时长

1.7 months

期刊介绍： Organometallics is the flagship journal of organometallic chemistry and records progress in one of the most active fields of science, bridging organic and inorganic chemistry. The journal publishes Articles, Communications, Reviews, and Tutorials (instructional overviews) that depict research on the synthesis, structure, bonding, chemical reactivity, and reaction mechanisms for a variety of applications, including catalyst design and catalytic processes; main-group, transition-metal, and lanthanide and actinide metal chemistry; synthetic aspects of polymer science and materials science; and bioorganometallic chemistry.