Flash Communication: Multinuclear Zwitterionic Germylene with Ge4 Chain Motif

IF 2.9 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Organometallics Pub Date : 2025-07-29 DOI:10.1021/acs.organomet.5c00118

Jicheng Wang, Sonam Suthar, Ming Li, Manbo Zhang, Kartik Chandra Mondal*, Hongping Zhu* and Bin Li*,

引用次数: 0

Abstract

A multinuclear germylene complex 2 was afforded by reacting the ylide-like N-heterocyclic germylene LGe (L = CH{(C═CH₂)(CMe)[N(Ar)]₂}, Ar = 2,6-iPr₂C₆H₃) (1) with GeCl₂·dioxane. Complex 2 features a unique Ge₄ chain skeleton, which was constructed via 1,4-addition between germylene and GeCl₂, followed by the assembly of fragments. X-ray structural analysis and theoretical calculations illustrate the Ge–Ge bonding interaction and a zwitterionic character.

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闪烁通信：多核两性离子锗烯与Ge4链基序

由类叶利基N-杂环叶利基LGe (L = CH{(C = CH2)(CMe)[N(Ar)]2}, Ar = 2,6- ipr2c6h3)(1)与GeCl2·二氧六环反应得到多核叶利基配合物2。配合物2具有独特的Ge4链骨架，该骨架是通过在germylene和GeCl2之间进行1,4加成，然后进行片段组装而成。x射线结构分析和理论计算说明了Ge-Ge键相互作用和两性离子特征。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Organometallics 化学-无机化学与核化学

CiteScore

5.60

自引率

7.10%

发文量

382

审稿时长

1.7 months

期刊介绍： Organometallics is the flagship journal of organometallic chemistry and records progress in one of the most active fields of science, bridging organic and inorganic chemistry. The journal publishes Articles, Communications, Reviews, and Tutorials (instructional overviews) that depict research on the synthesis, structure, bonding, chemical reactivity, and reaction mechanisms for a variety of applications, including catalyst design and catalytic processes; main-group, transition-metal, and lanthanide and actinide metal chemistry; synthetic aspects of polymer science and materials science; and bioorganometallic chemistry.