Structural and Gas Uptake Studies on Iron(II) β-Diketiminate Metallomacrocycles

IF 2.9 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Organometallics Pub Date : 2025-08-01 DOI:10.1021/acs.organomet.5c00208

Adam N. Barrett, Leah Webster, Danila Gasperini, Rémi Castaing, Mary F. Mahon* and Ruth L. Webster*,

引用次数: 0

Abstract

Three iron metallomacrocycles were synthesized and characterized using single crystal X-ray crystallography. Varying the amide coligand allows for macrocycles containing three, four, or six iron centers. The metallomacrocycles show extended structures in the solid state that are reminiscent of metal-organic framework structures; thus, the adsorbative properties of the complexes in the solid state have been investigated using N₂. Based on the data, three metallomacrocyles display classical type II isotherms and pore size distributions synonymous with mesoporous materials.

查看原文本刊更多论文

铁(II) β-二氯胺酸盐金属大环的结构和气体吸收研究

合成了三个铁金属大环，并用单晶x射线晶体学对其进行了表征。改变酰胺配体允许包含三个，四个或六个铁中心的大环。金属宏观环在固体状态下表现出与金属有机骨架结构相似的延伸结构；因此，用N2研究了配合物在固体状态下的吸附性能。结果表明，三个金属巨旋回具有典型的II型等温线和介孔材料的孔径分布特征。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Organometallics 化学-无机化学与核化学

CiteScore

5.60

自引率

7.10%

发文量

382

审稿时长

1.7 months

期刊介绍： Organometallics is the flagship journal of organometallic chemistry and records progress in one of the most active fields of science, bridging organic and inorganic chemistry. The journal publishes Articles, Communications, Reviews, and Tutorials (instructional overviews) that depict research on the synthesis, structure, bonding, chemical reactivity, and reaction mechanisms for a variety of applications, including catalyst design and catalytic processes; main-group, transition-metal, and lanthanide and actinide metal chemistry; synthetic aspects of polymer science and materials science; and bioorganometallic chemistry.