Weihua Wang, Wenjie Xu, Nan Zhang, Mingming Chen, Jingqing Zhang, Hongxing Liu, Jianqiang Wang, Yongfeng Hu
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引用次数: 0
Abstract
The purpose of this study is to develop novel P-Mo-V heteropoly compound catalysts for the oxidation of methacrolein to methacrylic acid. The introduction of Cu, as a modifying element, was employed to enhance the catalytic performance. Experimental results show that the addition of Cu significantly improved the catalyst performance, increasing the conversion rate of methacrolein from 17.2% to 84.2%, while the yield of methacrylic acid was boosted from 5.5% to 51.7%. A series of characterization results showed that both P-Mo-V and Cu-P-Mo-V catalysts primarily exhibited the crystal phase of [PMo12O40]3−, with a small amount of [PMo11VO40]3− phase. However, the Cu-P-Mo-V catalyst exhibited much better oxidation–reduction ability compared to the P-Mo-V catalyst. Isolated Cu atoms were found to exist in a highly decentralized tetrahedral coordination structure, bridged by oxygen atoms within the heteropoly compound framework. The addition of Cu resulted in notable alterations in the modulation of the surface electronic structure, enhancement of oxidation–reduction ability, and optimization of the reaction pathway, thereby improving the overall catalytic activity of the catalyst. This study not only provides new insights into the modification of P-Mo-V heteropoly compound catalysts but also lays a foundation for understanding their catalytic mechanisms in organic synthesis reactions, demonstrating the potential of modifying elements in improving catalyst performance.
期刊介绍:
Energy & Environmental Materials (EEM) is an international journal published by Zhengzhou University in collaboration with John Wiley & Sons, Inc. The journal aims to publish high quality research related to materials for energy harvesting, conversion, storage, and transport, as well as for creating a cleaner environment. EEM welcomes research work of significant general interest that has a high impact on society-relevant technological advances. The scope of the journal is intentionally broad, recognizing the complexity of issues and challenges related to energy and environmental materials. Therefore, interdisciplinary work across basic science and engineering disciplines is particularly encouraged. The areas covered by the journal include, but are not limited to, materials and composites for photovoltaics and photoelectrochemistry, bioprocessing, batteries, fuel cells, supercapacitors, clean air, and devices with multifunctionality. The readership of the journal includes chemical, physical, biological, materials, and environmental scientists and engineers from academia, industry, and policy-making.