Effect of steam-rich environments on the tribological performance of Cr2O3 coatings at high temperatures

IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL
Wear Pub Date : 2025-07-28 DOI:10.1016/j.wear.2025.206277
Matheus S. Pinto , Andre R. Mayer , Christian Moreau , Pantcho Stoyanov
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引用次数: 0

Abstract

This study investigates the tribological performance of a chromium oxide (Cr2O3) coating sliding against Inconel 718 at room temperature and at 450 °C, both without steam and in a steam-rich environment. A custom setup was used to generate and apply superheated steam at 200 °C during reciprocating ball-on-flat sliding tests. Surface analyses were carried out using 3D laser microscopy, SEM, and Raman spectroscopy. The Cr2O3 coating showed high wear resistance under all test conditions, and only the Inconel 718 counterballs exhibited measurable wear. Under conditions without steam, increasing the temperature led to lower friction and wear, which is associated with the formation of an oxide-based layer formed from counterball debris. When steam was present, the effect depended on the temperature. At room temperature, steam condensed on the surface, reducing contact between the materials and contributing to lower friction and wear. At 450 °C, the steam did not condense and interfered with the formation of a uniform oxide-based layer. This resulted in higher friction and localized wear in exposed regions of the interface. These findings support the potential of Cr2O3 coatings for use in harsh environments, such as hydrogen-fueled gas turbines, where both high temperature and steam exposure are present.
富蒸汽环境对Cr2O3涂层高温摩擦学性能的影响
本研究研究了在室温和450°C下,无蒸汽和富蒸汽环境下,氧化铬(Cr2O3)涂层与Inconel 718滑动的摩擦学性能。在往复球对平面滑动测试中,使用定制设置来产生和施加200°C的过热蒸汽。表面分析采用三维激光显微镜、扫描电镜和拉曼光谱进行。Cr2O3涂层在所有测试条件下都表现出较高的耐磨性,只有Inconel 718反球表现出可测量的磨损。在没有蒸汽的条件下,提高温度可以降低摩擦和磨损,这与由反球碎屑形成的氧化基层有关。当有蒸汽存在时,效果取决于温度。在室温下,蒸汽在表面凝结,减少了材料之间的接触,有助于降低摩擦和磨损。在450°C时,蒸汽不凝结,妨碍了均匀的氧化基层的形成。这导致了更高的摩擦和界面暴露区域的局部磨损。这些发现支持了Cr2O3涂层在恶劣环境中的应用潜力,例如氢燃料燃气轮机,在高温和蒸汽暴露中存在。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Wear
Wear 工程技术-材料科学:综合
CiteScore
8.80
自引率
8.00%
发文量
280
审稿时长
47 days
期刊介绍: Wear journal is dedicated to the advancement of basic and applied knowledge concerning the nature of wear of materials. Broadly, topics of interest range from development of fundamental understanding of the mechanisms of wear to innovative solutions to practical engineering problems. Authors of experimental studies are expected to comment on the repeatability of the data, and whenever possible, conduct multiple measurements under similar testing conditions. Further, Wear embraces the highest standards of professional ethics, and the detection of matching content, either in written or graphical form, from other publications by the current authors or by others, may result in rejection.
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