{"title":"Erosion behavior of TiC and Cu-TiC contact materials under vacuum arc","authors":"Peng Zhang , Heng Xie","doi":"10.1016/j.ceramint.2025.04.312","DOIUrl":null,"url":null,"abstract":"<div><div>TiC compact and Cu-TiC composites were fabricated by Spark Plasma Sintering and their arc erosion behavior in vacuum was investigated in detail. It was found that TiC cathode becomes brittle and cracks easily during the arc erosion process, and TiC particles in Cu-TiC cathodes also exhibit similar behavior. After the first vacuum breakdown, erosion pits are mostly concentrated on the TiC particles at Cu-TiC cathode. After the repeated vacuum breakdowns, TiC particles are more easily eroded than the Cu matrix. In the arc-eroded zone, TiC particles are melted before Cu. Thermal cracks are developed not only inside the TiC particles but also at the interface of Cu and TiC. Both Ti and C can be found as the decomposition products of TiC under vacuum arc erosion. The obtained results suggest that a moderate amount of TiC addition (less than 5 %) can effectively disperse the arc and protect the Cu matrix from arc erosion. An excessive TiC addition is harmful since TiC has the possibility to be broken into small fragments and suffers severe ablation under cathodic arcs.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"51 20","pages":"Pages 31246-31258"},"PeriodicalIF":5.6000,"publicationDate":"2025-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0272884225019820","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0
Abstract
TiC compact and Cu-TiC composites were fabricated by Spark Plasma Sintering and their arc erosion behavior in vacuum was investigated in detail. It was found that TiC cathode becomes brittle and cracks easily during the arc erosion process, and TiC particles in Cu-TiC cathodes also exhibit similar behavior. After the first vacuum breakdown, erosion pits are mostly concentrated on the TiC particles at Cu-TiC cathode. After the repeated vacuum breakdowns, TiC particles are more easily eroded than the Cu matrix. In the arc-eroded zone, TiC particles are melted before Cu. Thermal cracks are developed not only inside the TiC particles but also at the interface of Cu and TiC. Both Ti and C can be found as the decomposition products of TiC under vacuum arc erosion. The obtained results suggest that a moderate amount of TiC addition (less than 5 %) can effectively disperse the arc and protect the Cu matrix from arc erosion. An excessive TiC addition is harmful since TiC has the possibility to be broken into small fragments and suffers severe ablation under cathodic arcs.
期刊介绍:
Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties.
Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour.
Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.