Elusive no more: Gold–phosphane tellurides illuminate heavy chalcogen bonding and activation

IF 19.6 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chem Pub Date : 2025-07-31 DOI:10.1016/j.chempr.2025.102689

Antonio Frontera

引用次数: 0

Abstract

Reporting in Cell Reports Physical Science, Gimeno and co-workers isolate elusive gold–phosphane tellurides and uncover how metal coordination reshapes tellurium bonding, reactivity, and σ-hole-driven catalysis, offering insights into decomposition pathways and chalcogen bond activation.

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难以捉摸的不再是：金-磷化碲照亮重碳键和活化

在《细胞报告-物理科学》杂志上，Gimeno及其同事分离了难以捉摸的金-磷化碲化物，并揭示了金属配位如何重塑碲键、反应性和σ-孔驱动的催化作用，为分解途径和硫键激活提供了见解。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chem Environmental Science-Environmental Chemistry

CiteScore

32.40

自引率

1.30%

发文量

281

期刊介绍： Chem, affiliated with Cell as its sister journal, serves as a platform for groundbreaking research and illustrates how fundamental inquiries in chemistry and its related fields can contribute to addressing future global challenges. It was established in 2016, and is currently edited by Robert Eagling.