A corrosion-resistant and OER active stainless steel anode for water splitting in acidic Media

Abstract

The development of cost-effective and durable anode materials is crucial for advancing proton exchange membrane (PEM) water electrolysis. In this study, we demonstrate a simple thermal oxidation approach to activate a manganese-cobalt-containing stainless steel for the oxygen evolution reaction (OER) in 0.1 M HClO₄. The surface-modified stainless steel exhibits a low overpotential of 440 mV at 10 mA/cm² while maintaining a faradaic efficiency of 99.9 %. Long-term chronopotentiometry at 10 mA/cm² confirms stable operation for over 100 h without significant degradation. Comparative structural analysis on the stainless steel without Co reveals that the enhanced performance originates from a dual-layer structure composed of crystalline α-Mn₂O₃ nanoparticles and a Co-rich interfacial layer. The α-Mn₂O₃ phase provides abundant catalytically active Mn³⁺ sites, while the Co-rich layer maintains structural integrity and electron conductivity by strongly bridging the oxide surface to the matrix. By leveraging mature steel-manufacturing processes, this work presents a scalable and low-cost strategy to fabricate non-noble-metal steel anodes through a simple one-step heat treatment process, highlighting a promising pathway toward more affordable green hydrogen production.