{"title":"Up-conversion of 780 nm or 795 nm laser radiation to 420 nm in rubidium atomic vapor","authors":"Armen Sargsyan, Anahit Gogyan, David Sarkisyan","doi":"10.1016/j.sab.2025.107282","DOIUrl":null,"url":null,"abstract":"<div><div>We demonstrate efficient laser-induced fluorescence (LIF) at 420 nm — corresponding to the Rb <span><math><mrow><mn>6</mn><msub><mrow><mi>P</mi></mrow><mrow><mn>3</mn><mo>/</mo><mn>2</mn></mrow></msub><mo>→</mo><mn>5</mn><msub><mrow><mi>S</mi></mrow><mrow><mn>1</mn><mo>/</mo><mn>2</mn></mrow></msub></mrow></math></span> transition — induced by 780 nm or 795 nm laser radiation, which is nearly resonant via a two-photon excitation pathway involving the <span><math><mrow><mn>5</mn><msub><mrow><mi>S</mi></mrow><mrow><mn>1</mn><mo>/</mo><mn>2</mn></mrow></msub><mo>→</mo><mn>5</mn><msub><mrow><mi>D</mi></mrow><mrow><mn>3</mn><mo>/</mo><mn>2</mn></mrow></msub></mrow></math></span> transition. We use a 1-cm-long T-shaped all-sapphire cells containing Rb vapor and different pressures of Ne buffer gas. The dependence of 420 nm LIF intensity on temperature, buffer gas pressure, and excitation wavelength is analyzed. The optimal conditions for achieving bright blue-violet emission are established. Practical applications of this up-conversion process are discussed. The results demonstrate the potential for using Rb vapor cells as compact and efficient optical up-conversion filters, converting near-infrared laser radiation into visible blue emission.</div></div>","PeriodicalId":21890,"journal":{"name":"Spectrochimica Acta Part B: Atomic Spectroscopy","volume":"233 ","pages":"Article 107282"},"PeriodicalIF":3.8000,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta Part B: Atomic Spectroscopy","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0584854725001673","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"SPECTROSCOPY","Score":null,"Total":0}
引用次数: 0
Abstract
We demonstrate efficient laser-induced fluorescence (LIF) at 420 nm — corresponding to the Rb transition — induced by 780 nm or 795 nm laser radiation, which is nearly resonant via a two-photon excitation pathway involving the transition. We use a 1-cm-long T-shaped all-sapphire cells containing Rb vapor and different pressures of Ne buffer gas. The dependence of 420 nm LIF intensity on temperature, buffer gas pressure, and excitation wavelength is analyzed. The optimal conditions for achieving bright blue-violet emission are established. Practical applications of this up-conversion process are discussed. The results demonstrate the potential for using Rb vapor cells as compact and efficient optical up-conversion filters, converting near-infrared laser radiation into visible blue emission.
期刊介绍:
Spectrochimica Acta Part B: Atomic Spectroscopy, is intended for the rapid publication of both original work and reviews in the following fields:
Atomic Emission (AES), Atomic Absorption (AAS) and Atomic Fluorescence (AFS) spectroscopy;
Mass Spectrometry (MS) for inorganic analysis covering Spark Source (SS-MS), Inductively Coupled Plasma (ICP-MS), Glow Discharge (GD-MS), and Secondary Ion Mass Spectrometry (SIMS).
Laser induced atomic spectroscopy for inorganic analysis, including non-linear optical laser spectroscopy, covering Laser Enhanced Ionization (LEI), Laser Induced Fluorescence (LIF), Resonance Ionization Spectroscopy (RIS) and Resonance Ionization Mass Spectrometry (RIMS); Laser Induced Breakdown Spectroscopy (LIBS); Cavity Ringdown Spectroscopy (CRDS), Laser Ablation Inductively Coupled Plasma Atomic Emission Spectroscopy (LA-ICP-AES) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS).
X-ray spectrometry, X-ray Optics and Microanalysis, including X-ray fluorescence spectrometry (XRF) and related techniques, in particular Total-reflection X-ray Fluorescence Spectrometry (TXRF), and Synchrotron Radiation-excited Total reflection XRF (SR-TXRF).
Manuscripts dealing with (i) fundamentals, (ii) methodology development, (iii)instrumentation, and (iv) applications, can be submitted for publication.