One-pot synthesis of atomically precise chiral PtAg4 nanoclusters

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-07-30 DOI:10.1039/d5cc03572d

Yujie Zhang , Hongli Jia , Bingzheng Yan , Jian Hou , Huifang Guo , Qi Li , Chengrui Xin , Simin Li , Jinrun Dong , Hui Shen

引用次数: 0

Abstract

We report the synthesis and structural characterization of [PtAg₄Cl(BDPP)₄H]²⁺, a novel bimetallic complex featuring an intrinsically chiral architecture. The heterometallic Pt–Ag core exhibits distinctive optical properties, while the chiral BDPP (BDPP is 2,4-bis(diphenylphosphino)pentane) ligand not only induces structural asymmetry but also fine-tunes the electronic and steric characteristics of the complex.

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原子精密手性PtAg4纳米团簇的一锅合成

本文报道了一种具有固有手性结构的新型双金属配合物PtAg4Cl(BDPP)4H]2+的合成和结构表征。而手性BDPP （BDPP为2,4-二（二苯基膦）戊烷）配体不仅可以诱导结构不对称，还可以微调配合物的电子和空间特性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.