Cover Feature: Pd[B(S2O7)2]2 and Pd[B(SO4) (S2O7)]2: Two Borosulfates with Pd2+ in Octahedral and One with Pd2+ in Square Planar Oxygen Coordination

IF 3.9 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemistry - A European Journal Pub Date : 2025-07-26 DOI:10.1002/chem.202584102

Stefan Sutorius, David Patrun, Arthur Edelmann, Lars Schumacher, Rainer Pöttgen, Markus Suta, Jörn Bruns

引用次数: 0

Abstract

Three different palladium borosulfates have been synthesized by the reaction of elemental palladium with B₂O₃ and SO₃. The compounds exhibit Pd²⁺ cations either in typical square-planar or even in octahedral oxygen coordination. The latter results in the formation of blue crystals, whereas the former forms red crystals. Due to the d⁸ high-spin configuration, the blue species are paramagnetic. More information can be found in the Research Article by R. Pöttgen, M. Suta, J. Bruns and co-workers (DOI: 10.1002/chem.202501515).

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封面特征：Pd[B(S2O7)2]2和Pd[B(SO4) (S2O7)]2：两种具有八面体Pd2+的硼硫酸盐和一种具有方形平面氧配位的Pd2+

以单质钯与B2O3和SO3反应合成了三种不同的硼硫酸钯。这些化合物在典型的方平面或八面体氧配位中均表现出Pd2+阳离子。后者形成蓝色晶体，而前者形成红色晶体。由于d8的高自旋构型，蓝色物质是顺磁性的。更多信息可以在R. Pöttgen， M. Suta， J. Bruns和同事的研究文章中找到（DOI: 10.1002/chem.202501515）。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemistry - A European Journal 化学-化学综合

CiteScore

7.90

自引率

4.70%

发文量

1808

审稿时长

1.8 months

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