3D printing of bio-based photocurable slurries prepared with waste-derived glass

IF 9.2 2区工程技术 Q1 ENERGY & FUELS

Sustainable Materials and Technologies Pub Date : 2025-07-18 DOI:10.1016/j.susmat.2025.e01549

Matilde Porcarello, Marco Sangermano, Milena Salvo, Federico Smeacetto, Simone Anelli

{"title":"3D printing of bio-based photocurable slurries prepared with waste-derived glass","authors":"Matilde Porcarello, Marco Sangermano, Milena Salvo, Federico Smeacetto, Simone Anelli","doi":"10.1016/j.susmat.2025.e01549","DOIUrl":null,"url":null,"abstract":"<div><div>This study investigates waste-derived glass materials in 3D printing slurries through vat polymerization technologies, utilizing biobased photocurable formulations derived from acrylate epoxidized soybean oil (AESO). Waste materials, including mineral wool and glass from municipal waste incinerator bottom ash vitrification, were milled, sieved, and characterized to ensure a particle size distribution under 50 μm. Thermal analyses were conducted to understand the glass-based materials' thermal behavior and the polymeric formulation's decomposition, allowing for the optimization of thermal treatment parameters. These powders were mixed with AESO formulations to create photocurable slurries containing up to 60 wt% ceramic loadings. Rheological and photo-rheological tests demonstrated satisfactory flowability (0.2–10 Pa·s) and high photo reactivity for 3D printing. Subsequently, thermal treatments at 950 °C were applied to consolidate the printed objects, removing the resin component and forming glass-ceramic structures. The results highlight the significant potential of this method for producing porous glass-ceramic materials, offering promising opportunities for sustainable material reuse and advanced manufacturing processes.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"45 ","pages":"Article e01549"},"PeriodicalIF":9.2000,"publicationDate":"2025-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Sustainable Materials and Technologies","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2214993725003173","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENERGY & FUELS","Score":null,"Total":0}

引用次数: 0

Abstract

This study investigates waste-derived glass materials in 3D printing slurries through vat polymerization technologies, utilizing biobased photocurable formulations derived from acrylate epoxidized soybean oil (AESO). Waste materials, including mineral wool and glass from municipal waste incinerator bottom ash vitrification, were milled, sieved, and characterized to ensure a particle size distribution under 50 μm. Thermal analyses were conducted to understand the glass-based materials' thermal behavior and the polymeric formulation's decomposition, allowing for the optimization of thermal treatment parameters. These powders were mixed with AESO formulations to create photocurable slurries containing up to 60 wt% ceramic loadings. Rheological and photo-rheological tests demonstrated satisfactory flowability (0.2–10 Pa·s) and high photo reactivity for 3D printing. Subsequently, thermal treatments at 950 °C were applied to consolidate the printed objects, removing the resin component and forming glass-ceramic structures. The results highlight the significant potential of this method for producing porous glass-ceramic materials, offering promising opportunities for sustainable material reuse and advanced manufacturing processes.

查看原文本刊更多论文

用废弃玻璃制备的生物基光固化浆料的3D打印

本研究通过还原聚合技术，利用源自丙烯酸酯环氧大豆油（AESO）的生物基光固化配方，研究了3D打印浆料中废物衍生的玻璃材料。对城市垃圾焚烧炉底灰玻璃化产生的矿物棉和玻璃等废弃物进行了研磨、筛分和表征，确保粒径分布在50 μm以下。进行热分析以了解玻璃基材料的热行为和聚合物配方的分解，从而优化热处理参数。这些粉末与AESO配方混合，形成含有高达60%陶瓷负载的光固化浆料。流变学和光流变学测试表明，3D打印材料具有良好的流动性（0.2-10 Pa·s）和光反应性。随后，在950°C下进行热处理以巩固打印对象，去除树脂成分并形成玻璃陶瓷结构。结果强调了这种方法在生产多孔玻璃陶瓷材料方面的巨大潜力，为可持续材料再利用和先进制造工艺提供了有希望的机会。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Sustainable Materials and Technologies Energy-Renewable Energy, Sustainability and the Environment

CiteScore

13.40

自引率

4.20%

发文量

158

审稿时长

45 days

期刊介绍： Sustainable Materials and Technologies (SM&T), an international, cross-disciplinary, fully open access journal published by Elsevier, focuses on original full-length research articles and reviews. It covers applied or fundamental science of nano-, micro-, meso-, and macro-scale aspects of materials and technologies for sustainable development. SM&T gives special attention to contributions that bridge the knowledge gap between materials and system designs.