Innovative Strategies for Oxygen Evolution Reaction Using Layered Double Hydroxide-Based Electrocatalysts

IF 1.9 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Zifeng Li, Honglin Gao, Li Che, Aiyi Dong
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引用次数: 0

Abstract

Layered double hydroxides (LDH) catalysts are widely used in oxygen evolution reaction (OER), but are limited by their low conductivity, few active sites, and poor stability. For this reason, various modification strategies have emerged. In this review, the mechanistic explanation direction of the OER performance enhancement of modified LDH was elaborated from a mechanistic point of view, which mainly includes the heterostructure-dominated synergistic effect, doping-induced lattice distortion and multi-element electronic interaction. The substantial improvements in OER performance achieved through LDH modification can be considered by focusing on the above three mechanisms. Subsequently, a detailed exploration of the existing shortcomings in the explanation of LDH modification mechanisms for OER was conducted. By addressing these gaps, we aim to offer more effective guidance for the rational design and broad application of LDH-based catalysts in OER processes in the future.

Abstract Image

层状双氧水基电催化剂析氧反应的创新策略
层状双氢氧化物(LDH)催化剂在析氧反应(OER)中得到了广泛的应用,但由于其电导率低、活性位点少、稳定性差而受到限制。因此,出现了各种修改策略。本文从机理的角度阐述了改性LDH OER性能增强的机理解释方向,主要包括异质结构主导的协同效应、掺杂诱导的晶格畸变和多元素电子相互作用。通过LDH改性实现的OER性能的实质性改进可以通过关注上述三种机制来考虑。随后,详细探讨了LDH修饰OER机理解释中存在的不足。通过解决这些空白,我们的目标是为未来在OER工艺中合理设计和广泛应用ldh基催化剂提供更有效的指导。
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来源期刊
ChemistrySelect
ChemistrySelect Chemistry-General Chemistry
CiteScore
3.30
自引率
4.80%
发文量
1809
审稿时长
1.6 months
期刊介绍: ChemistrySelect is the latest journal from ChemPubSoc Europe and Wiley-VCH. It offers researchers a quality society-owned journal in which to publish their work in all areas of chemistry. Manuscripts are evaluated by active researchers to ensure they add meaningfully to the scientific literature, and those accepted are processed quickly to ensure rapid online publication.
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