Selective Electrochemical Reduction of CO2 to Metal Oxalates in Nonaqueous Solutions Using Trace Metal Pb on Carbon Supports Enhanced by a Tailored Microenvironment (Adv. Energy Mater. 28/2025)

IF 26 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Advanced Energy Materials Pub Date : 2025-07-22 DOI:10.1002/aenm.202570125

Rowan S. Brower, Brian Wuille Bille, Shawn Chiu, Joseph T. Perryman, Libo Yao, Faridat O. Agboola, Cocoro A. Nagasaka, Yinuo Xie, Richard Gomez-Caballero, Ankita Kumari, Elizabeth K. Neumann, Anastassia N. Alexandrova, Charles C. L. McCrory, Jesus M. Velázquez

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Abstract

Reduction of CO₂

Incorporating trace lead catalysts at parts-per-billion metal loadings onto carbon supports with polymer overlayers enables selective electrochemical reduction of CO₂ to solid oxalates with activity rivaling the performance of bulk lead electrocatalysts. This microenvironment strategy transforms trace metals into efficient carbon-conversion catalysts, providing a scalable route to integrate CO₂ utilization with industrial materials production such as sustainable cement alternatives. More in article number 2501286, Anastassia N. Alexandrova, Charles C. L. McCrory, Jesus M. Velázquez, and co-workers.

Abstract Image

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微环境增强碳载体上痕量金属Pb在非水溶液中选择性电化学还原CO2为金属草酸盐的研究（能源材料，28/2025）

将微量铅催化剂以十亿分之一的金属负荷与聚合物覆盖层结合到碳载体上，可以选择性地将二氧化碳电化学还原为固体草酸盐，其活性可与散装铅电催化剂的性能相媲美。这种微环境策略将微量金属转化为高效的碳转化催化剂，为将二氧化碳利用与可持续水泥替代品等工业材料生产相结合提供了可扩展的途径。更多文章编号2501286，Anastassia N. Alexandrova, Charles C. L. McCrory, Jesus M. Velázquez和同事。

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来源期刊

Advanced Energy Materials CHEMISTRY, PHYSICAL-ENERGY & FUELS

CiteScore

41.90

自引率

4.00%

发文量

889

审稿时长

1.4 months

期刊介绍： Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small. With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics. The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.