José R. González-Jiménez , F. Javier Jiménez-Romero , M. Carmen López-Luna , Álvaro Bonilla , Álvaro Caballero
{"title":"Dynamic polarization control unlocks long-life, high-efficiency Lithium-Sulfur batteries","authors":"José R. González-Jiménez , F. Javier Jiménez-Romero , M. Carmen López-Luna , Álvaro Bonilla , Álvaro Caballero","doi":"10.1016/j.apenergy.2025.126501","DOIUrl":null,"url":null,"abstract":"<div><div>Lithium‑sulfur (Li<img>S) batteries offer exceptional theoretical capacity and energy density but are hindered in practice by sluggish reaction kinetics and severe polarization effects. Here, we introduce a pioneering Polarization-Controlled Charging Protocol (PPC) that dynamically adjusts the charging current in real time by maintaining a constant polarization threshold. This strategy accelerates charging in kinetically favorable regimes while suppressing current in polarization-prone regions, thereby preserving electrode structure and extending cycle life. The PPC yields a linear voltage-time charging profile, enabling direct state-of-charge (SOC) estimation and accurate charging time prediction. Average long-term cycling demonstrates that PPC can double battery lifespan. Compared to constant-current charging (CC), PPC achieves over 800 stable cycles at selected C-rates, while CC leads to faster capacity fading. The found average Li diffusion coefficient in PPC is seven times higher than that of the CC conditions, supporting hasted reaction kinetics. Overall, PPC reduces degradation by ∼69 % under equivalent average kinetics conditions, and offers a non-chemical, kinetics-responsive strategy to enhance durability, efficiency, and control in Li<img>S batteries, with strong relevance for high-demand applications such as electric mobility.</div></div>","PeriodicalId":246,"journal":{"name":"Applied Energy","volume":"399 ","pages":"Article 126501"},"PeriodicalIF":10.1000,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Energy","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0306261925012310","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
Abstract
Lithium‑sulfur (LiS) batteries offer exceptional theoretical capacity and energy density but are hindered in practice by sluggish reaction kinetics and severe polarization effects. Here, we introduce a pioneering Polarization-Controlled Charging Protocol (PPC) that dynamically adjusts the charging current in real time by maintaining a constant polarization threshold. This strategy accelerates charging in kinetically favorable regimes while suppressing current in polarization-prone regions, thereby preserving electrode structure and extending cycle life. The PPC yields a linear voltage-time charging profile, enabling direct state-of-charge (SOC) estimation and accurate charging time prediction. Average long-term cycling demonstrates that PPC can double battery lifespan. Compared to constant-current charging (CC), PPC achieves over 800 stable cycles at selected C-rates, while CC leads to faster capacity fading. The found average Li diffusion coefficient in PPC is seven times higher than that of the CC conditions, supporting hasted reaction kinetics. Overall, PPC reduces degradation by ∼69 % under equivalent average kinetics conditions, and offers a non-chemical, kinetics-responsive strategy to enhance durability, efficiency, and control in LiS batteries, with strong relevance for high-demand applications such as electric mobility.
期刊介绍:
Applied Energy serves as a platform for sharing innovations, research, development, and demonstrations in energy conversion, conservation, and sustainable energy systems. The journal covers topics such as optimal energy resource use, environmental pollutant mitigation, and energy process analysis. It welcomes original papers, review articles, technical notes, and letters to the editor. Authors are encouraged to submit manuscripts that bridge the gap between research, development, and implementation. The journal addresses a wide spectrum of topics, including fossil and renewable energy technologies, energy economics, and environmental impacts. Applied Energy also explores modeling and forecasting, conservation strategies, and the social and economic implications of energy policies, including climate change mitigation. It is complemented by the open-access journal Advances in Applied Energy.