Copper‐Catalyzed Constructions of 4‐(2‐Arylhydrazono) isochroman‐3‐imines from 4‐Diazoisochroman‐3‐imines and Arylboronic Acids

IF 2.7 3区化学 Q2 CHEMISTRY, ORGANIC

European Journal of Organic Chemistry Pub Date : 2025-09-23 DOI:10.1002/ejoc.202500246

Junrong Chen , Minghui Qi , Ping Lu , Yanguang Wang

引用次数: 0

Abstract

A novel copper‐catalyzed reaction of 4‐diazoisochroman‐3‐imines and arylboronic acids is reported. This transformation efficiently yields 4‐(2‐aryl)hydrazono)isochroman‐3‐imines under mild reaction conditions, showcasing excellent substrate scope and functional group tolerance. Additionally, the versatility of this approach extends to other cyclic diazo compounds, broadening its applicability.

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铜催化从4 -重氮异染色质- 3 -亚胺和芳基硼酸合成4 -（2 -芳基腙）异染色质- 3 -亚胺

报道了一种新的铜催化4 -重氮异色胺- 3 -亚胺和芳基硼酸的反应。该转化在温和的反应条件下有效地生成4‐（2‐芳基）腙)等色man‐3‐亚胺，具有良好的底物范围和官能团耐受性。此外，这种方法的多功能性延伸到其他环重氮化合物，扩大了其适用性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

European Journal of Organic Chemistry 化学-有机化学

CiteScore

5.40

自引率

3.60%

发文量

752

审稿时长

1 months

期刊介绍： The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.