Hierarchical work function programming for optimizing interfacial polarization in electromagnetic wave absorber

IF 9.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chinese Chemical Letters Pub Date : 2025-05-09 DOI:10.1016/j.cclet.2025.111293

Jinkun Liu , Xuelian Yang , Wenxuan Chen , Pingan Zhu , Guanglei Wu , Jing Zheng , Xu Hou

{"title":"Hierarchical work function programming for optimizing interfacial polarization in electromagnetic wave absorber","authors":"Jinkun Liu , Xuelian Yang , Wenxuan Chen , Pingan Zhu , Guanglei Wu , Jing Zheng , Xu Hou","doi":"10.1016/j.cclet.2025.111293","DOIUrl":null,"url":null,"abstract":"<div><div>The development of next-generation electromagnetic wave (EMW) absorbers requires a shift in interface design. By employing hierarchical work function programming, we propose an approach to tune interfacial polarization dynamics. This method utilizes multi-gradient work functions to guide carrier migration and polarization effectively, thereby enhancing energy dissipation under alternating electromagnetic fields. Here, we constructed a 1T/2H-MoS<sub>2</sub>/PPy/VS<sub>2</sub> composite absorber with integrated gradient interfaces. The composite achieved a powerful absorption (RL<sub>min</sub>) of -58.59 dB at 2.3 mm, and an effective absorption bandwidth (EAB) of 7.44 GHz at 2.5 mm, demonstrating improved broadband absorption. Radar cross-section (RCS) simulations show an EMW loss of -7.2 dB m<sup>2</sup> at 0°, highlighting its potential for stealth and communication applications. This study introduces hierarchical work function programming as a promising strategy in EMW absorber design, contributing to advancements in material performance and functionality.</div></div>","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"36 10","pages":"Article 111293"},"PeriodicalIF":9.4000,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chinese Chemical Letters","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1001841725004784","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

The development of next-generation electromagnetic wave (EMW) absorbers requires a shift in interface design. By employing hierarchical work function programming, we propose an approach to tune interfacial polarization dynamics. This method utilizes multi-gradient work functions to guide carrier migration and polarization effectively, thereby enhancing energy dissipation under alternating electromagnetic fields. Here, we constructed a 1T/2H-MoS₂/PPy/VS₂ composite absorber with integrated gradient interfaces. The composite achieved a powerful absorption (RL_min) of -58.59 dB at 2.3 mm, and an effective absorption bandwidth (EAB) of 7.44 GHz at 2.5 mm, demonstrating improved broadband absorption. Radar cross-section (RCS) simulations show an EMW loss of -7.2 dB m² at 0°, highlighting its potential for stealth and communication applications. This study introduces hierarchical work function programming as a promising strategy in EMW absorber design, contributing to advancements in material performance and functionality.

Abstract Image

查看原文本刊更多论文

电磁波吸收器界面极化优化的分层功函数规划

下一代电磁波（EMW）吸收器的发展需要界面设计的转变。采用分层功函数编程，提出了一种调整界面极化动力学的方法。该方法利用多梯度功函数有效地引导载流子迁移和极化，从而增强交变电磁场下的能量耗散。在这里，我们构建了具有集成梯度界面的1T/2H-MoS2/PPy/VS2复合吸收体。该复合材料在2.3 mm处的强吸收（RLmin）为-58.59 dB，在2.5 mm处的有效吸收带宽（EAB）为7.44 GHz，显示出宽带吸收的改善。雷达横截面（RCS）模拟显示，在0°时EMW损耗为-7.2 dB m2，突出了其隐身和通信应用的潜力。本研究介绍了分层功函数编程作为EMW吸收器设计的一种有前途的策略，有助于材料性能和功能的进步。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Chinese Chemical Letters 化学-化学综合

CiteScore

14.10

自引率

15.40%

发文量

8969

审稿时长

1.6 months

期刊介绍： Chinese Chemical Letters (CCL) (ISSN 1001-8417) was founded in July 1990. The journal publishes preliminary accounts in the whole field of chemistry, including inorganic chemistry, organic chemistry, analytical chemistry, physical chemistry, polymer chemistry, applied chemistry, etc.Chinese Chemical Letters does not accept articles previously published or scheduled to be published. To verify originality, your article may be checked by the originality detection service CrossCheck.