Recent Advances in the Photocatalytic Defluorinative Functionalization of Trifluoromethyl Arenes and Trifluoromethyl Ketones via Radical Process

IF 2.8 4区化学 Q1 CHEMISTRY, ORGANIC

Asian Journal of Organic Chemistry Pub Date : 2025-07-01 DOI:10.1002/ajoc.202500257

Can Zeng , Yue Wang , Prof. Zhen Wang , Dr. Yao‐Fu Zeng

引用次数: 0

Abstract

Recent years have witnessed rapid growth in the C─F bond functionalization of trifluoromethyl arenes and trifluoromethyl carbonyl compounds, which has been promoted by the development of photoredox catalysis. In this review, the photocatalyzed C─F bond activation of trifluoromethyl arenes and trifluoromethyl carbonyl compounds via difluoromethyl radical intermediate has been covered. This review was categorized into three parts based on the activation modes of C─F bond. Several representative instances, in conjunction with the reaction mechanism, were also deliberated upon.

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自由基法光催化三氟甲基芳烃和三氟甲基酮去氟功能化研究进展

近年来，由于光氧化还原催化技术的发展，三氟甲基芳烃和三氟甲基羰基化合物的C─F键功能化得到了快速发展。本文综述了光催化三氟甲基芳烃和三氟甲基羰基化合物通过二氟甲基自由基中间体活化C─F键的研究进展。本文根据C─F键的激活方式分为三个部分。还结合反应机制审议了几个有代表性的事例。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Asian Journal of Organic Chemistry CHEMISTRY, ORGANIC-

CiteScore

4.70

自引率

3.70%

发文量

372

期刊介绍： Organic chemistry is the fundamental science that stands at the heart of chemistry, biology, and materials science. Research in these areas is vigorous and truly international, with three major regions making almost equal contributions: America, Europe and Asia. Asia now has its own top international organic chemistry journal—the Asian Journal of Organic Chemistry (AsianJOC) The AsianJOC is designed to be a top-ranked international research journal and publishes primary research as well as critical secondary information from authors across the world. The journal covers organic chemistry in its entirety. Authors and readers come from academia, the chemical industry, and government laboratories.