{"title":"Studies on electrical properties of PLD grown BiFeO3 - based layered MFIS heterostructure device","authors":"Akshay Panchasara , Urjitsinh Rathod , Sumana Hajra , Pruthaba Jadeja , Akshay Ranpariya , Savan Katba , Vanaraj Solanki , Mahesh Jivani , Ashish Ravalia","doi":"10.1016/j.chemphys.2025.112851","DOIUrl":null,"url":null,"abstract":"<div><div>The pulsed lase deposited layered based thin film heterostructured device have been fabricated in Ag (metal) / Ca doped BiFeO<sub>3</sub> (Ferroelectric) / SrTiO<sub>3</sub> (Insulator) / ZnO (Semiconductor) MFIS geometry on STO (100) single crystalline substrate. The X-ray diffraction measurement confirm the substrate-oriented growth of Ca doped BiFeO<sub>3</sub> and SrTiO<sub>3</sub> layer while growth of ZnO is in different geometry due to its different structure than substrate. Surface and microstructural characterization have been carried out using Atomic Force Microscopy measurements which indicates the homogenous grain growth of Ca doped BiFeO<sub>3</sub> and ZnO layer. Electrical properties of proposed Ca doped BiFeO<sub>3</sub> based MFIS heterostructure have been studied using frequency dependent dielectric, cyclic I-V behaviour (with and without UV illumination) and channel resistance measurements. To understand the electrical property of proposed device, various charge conduction mechanism has understood using the fitting of I-V data. In addition, role of Ca doped BiFeO<sub>3</sub> ferroelectric layer in the channel resistance is investigated.</div></div>","PeriodicalId":272,"journal":{"name":"Chemical Physics","volume":"598 ","pages":"Article 112851"},"PeriodicalIF":2.4000,"publicationDate":"2025-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Physics","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0301010425002526","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The pulsed lase deposited layered based thin film heterostructured device have been fabricated in Ag (metal) / Ca doped BiFeO3 (Ferroelectric) / SrTiO3 (Insulator) / ZnO (Semiconductor) MFIS geometry on STO (100) single crystalline substrate. The X-ray diffraction measurement confirm the substrate-oriented growth of Ca doped BiFeO3 and SrTiO3 layer while growth of ZnO is in different geometry due to its different structure than substrate. Surface and microstructural characterization have been carried out using Atomic Force Microscopy measurements which indicates the homogenous grain growth of Ca doped BiFeO3 and ZnO layer. Electrical properties of proposed Ca doped BiFeO3 based MFIS heterostructure have been studied using frequency dependent dielectric, cyclic I-V behaviour (with and without UV illumination) and channel resistance measurements. To understand the electrical property of proposed device, various charge conduction mechanism has understood using the fitting of I-V data. In addition, role of Ca doped BiFeO3 ferroelectric layer in the channel resistance is investigated.
期刊介绍:
Chemical Physics publishes experimental and theoretical papers on all aspects of chemical physics. In this journal, experiments are related to theory, and in turn theoretical papers are related to present or future experiments. Subjects covered include: spectroscopy and molecular structure, interacting systems, relaxation phenomena, biological systems, materials, fundamental problems in molecular reactivity, molecular quantum theory and statistical mechanics. Computational chemistry studies of routine character are not appropriate for this journal.