Transition metal infused magnetic nanocatalysts for the synthesis of biaryls through Suzuki-Miyaura coupling reaction

IF 2.2 3区化学 Q2 CHEMISTRY, ORGANIC

Tetrahedron Pub Date : 2025-07-07 DOI:10.1016/j.tet.2025.134813

Sumanth Hegde , Aakash Venkatesan , Aatika Nizam , Vasantha Veerappa Lakshmaiah , Suresh Babu Naidu Krishna

{"title":"Transition metal infused magnetic nanocatalysts for the synthesis of biaryls through Suzuki-Miyaura coupling reaction","authors":"Sumanth Hegde , Aakash Venkatesan , Aatika Nizam , Vasantha Veerappa Lakshmaiah , Suresh Babu Naidu Krishna","doi":"10.1016/j.tet.2025.134813","DOIUrl":null,"url":null,"abstract":"<div><div>Over the last three decades, there has been a growing interest in the Suzuki-Miyaura cross coupling reaction (SMCR) and its applications. This widely used powerful reaction provides a practical synthetic route for the direct formations of C(sp<sup>2</sup>)-C(sp<sup>2</sup>) bonds. The widespread popularity of Suzuki-Miyaura products highlights the importance of developing regenerable nanocatalysts within comprehensive green synthetic strategies. These nanocatalysts, often utilizing transition metals, provide a valuable route to these products. Increased research focus on regenerable nanocatalysts has led to the design of diverse magnetic nanoparticles, frequently functionalized with transition metals, aiming to optimize reaction efficiency and catalyst recovery. This review covers literature from 2017 onwards, focusing on magnetically separable nanocatalysts, particularly those based on palladium, nickel, cobalt, and copper nanoparticles, for their application in SMCR. A key emphasis is placed on nanocatalysts demonstrating high recyclability without compromising reaction yield.</div></div>","PeriodicalId":437,"journal":{"name":"Tetrahedron","volume":"185 ","pages":"Article 134813"},"PeriodicalIF":2.2000,"publicationDate":"2025-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0040402025003692","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}

引用次数: 0

Abstract

Over the last three decades, there has been a growing interest in the Suzuki-Miyaura cross coupling reaction (SMCR) and its applications. This widely used powerful reaction provides a practical synthetic route for the direct formations of C(sp²)-C(sp²) bonds. The widespread popularity of Suzuki-Miyaura products highlights the importance of developing regenerable nanocatalysts within comprehensive green synthetic strategies. These nanocatalysts, often utilizing transition metals, provide a valuable route to these products. Increased research focus on regenerable nanocatalysts has led to the design of diverse magnetic nanoparticles, frequently functionalized with transition metals, aiming to optimize reaction efficiency and catalyst recovery. This review covers literature from 2017 onwards, focusing on magnetically separable nanocatalysts, particularly those based on palladium, nickel, cobalt, and copper nanoparticles, for their application in SMCR. A key emphasis is placed on nanocatalysts demonstrating high recyclability without compromising reaction yield.

Abstract Image

查看原文本刊更多论文

过渡金属注入磁性纳米催化剂用于Suzuki-Miyaura偶联反应合成双芳烯

在过去的三十年里，人们对Suzuki-Miyaura交叉偶联反应（SMCR）及其应用越来越感兴趣。这种被广泛应用的强反应为直接生成C(sp2)-C（sp2）键提供了一条实用的合成途径。铃木-宫浦产品的广泛普及突出了在全面的绿色合成战略中开发可再生纳米催化剂的重要性。这些纳米催化剂通常使用过渡金属，为这些产品提供了有价值的途径。对可再生纳米催化剂的研究越来越多，导致了各种磁性纳米颗粒的设计，这些纳米颗粒经常被过渡金属功能化，旨在优化反应效率和催化剂回收率。本文综述了2017年以来的文献，重点介绍了磁性可分离纳米催化剂，特别是基于钯、镍、钴和铜纳米颗粒的纳米催化剂在SMCR中的应用。一个关键的重点放在纳米催化剂显示高可回收性而不影响反应收率。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Tetrahedron 化学-有机化学

CiteScore

3.90

自引率

4.80%

发文量

439

审稿时长

34 days

期刊介绍： Tetrahedron publishes full accounts of research having outstanding significance in the broad field of organic chemistry and its related disciplines, such as organic materials and bio-organic chemistry. Regular papers in Tetrahedron are expected to represent detailed accounts of an original study having substantially greater scope and details than that found in a communication, as published in Tetrahedron Letters. Tetrahedron also publishes thematic collections of papers as special issues and ''Reports'', commissioned in-depth reviews providing a comprehensive overview of a research area.